Answer:
The equilibrium value of [CO] is 1.04 M
Explanation:
Chemical equilibrium is the state to which a spontaneously evolving chemical system, in which a reversible chemical reaction takes place. When this situation is reached, it is observed that the concentrations of substances, both reagents and reaction products, they remain constant over time. That is, the rate of reaction of reagents to products is the same as that of products to reagents.
Reagent concentrations and products in equilibrium are related by the equilibrium constant Kc. Being:
aA + bB ⇔ cC + dD
![Kc=\frac{[C]^{c} *[D]^{d} }{[A]^{a} *[B]^{b} }](https://tex.z-dn.net/?f=Kc%3D%5Cfrac%7B%5BC%5D%5E%7Bc%7D%20%2A%5BD%5D%5E%7Bd%7D%20%7D%7B%5BA%5D%5E%7Ba%7D%20%2A%5BB%5D%5E%7Bb%7D%20%7D)
Then this constant Kces equals the multiplication of the concentrations of the products raised to their stoichiometric coefficients between the multiplication of the concentrations of the reactants also raised to their stoichiometric coefficients.
In this case:
![Kc=\frac{[CH_{3}OH ]}{[CO]*[H_{2} ]^{2} }](https://tex.z-dn.net/?f=Kc%3D%5Cfrac%7B%5BCH_%7B3%7DOH%20%5D%7D%7B%5BCO%5D%2A%5BH_%7B2%7D%20%5D%5E%7B2%7D%20%7D)
You know:
- Kc= 14.5
- [H₂]= 0.322 M
- [CH₃OH] =1.56 M
Replacing:
![14.5=\frac{1.56}{[CO]*0.322^{2} }](https://tex.z-dn.net/?f=14.5%3D%5Cfrac%7B1.56%7D%7B%5BCO%5D%2A0.322%5E%7B2%7D%20%7D)
Solving:
![[CO]=\frac{1.56}{14.5*0.322^{2} }](https://tex.z-dn.net/?f=%5BCO%5D%3D%5Cfrac%7B1.56%7D%7B14.5%2A0.322%5E%7B2%7D%20%7D)
[CO]= 1.04 M
The equilibrium value of [CO] is 1.04 M
Answer:
- m = 1,000/58.5
- b = - 1,000 / 58.5
1) Variables
- molarity: M
- density of the solution: d
- moles of NaCl: n₁
- mass of NaCl: m₁
- molar mass of NaCl: MM₁
- total volume in liters: Vt
- Volume of water in mililiters: V₂
- mass of water: m₂
2) Density of the solution: mass in grams / volume in mililiters
3) Mass of NaCl: m₁
Number of moles = mass in grams / molar mass
⇒ mass in grams = number of moles × molar mass
m₁ = n₁ × MM₁
4) Number of moles of NaCl: n₁
Molarity = number of moles / Volume of solution in liters
M = n₁ / Vt
⇒ n₁ = M × Vt
5) Substitue in the equation of m₁:
m₁ = M × Vt × MM₁
6) Substitute in the equation of density:
d = [M × Vt × MM₁ + m₂] / (1000Vt)
7) Simplify and solve for M
- d = M × Vt × MM₁ / (1000Vt) + m₂/ (1000Vt)
- d = M × MM₁ / (1000) + m₂/ (1000Vt)
Making the simplistic assumption that the dissolved NaCl(s) does not affect the volume of the solvent water means 1000Vt = V₂
- d = M × MM₁ / (1000) + m₂/ V₂
m₂/ V₂ is the density of water: 1.00 g/mL
- d = M × MM₁ / (1000) + 1.00 g/mL
- M × MM₁ / (1000) = d - 1.00 g/mL
- M = [1,000/MM₁] d - 1,000/ MM₁
8) Substituting MM₁ = 58.5 g/mol
- M = [1,000/58.5] d - [1,000/ 58.5]
Comparing with the equation Molarity = m×density + b, you obtain:
- m = 1,000/58.5
- b = - 1,000/58.5
Answer:
The rate is a mathematical relationship obtained by comparing reaction rate with reactant concentrations.
Answer:
Option D. AlCl₃, MgC₂
Explanation:
We need to dissociate all the salts, to determine the i. (Van't Hoff factor).
The salt who has the highest value, will be the better conductor of electricity
CsCl → Cs⁺ + Cl⁻ i = 2
CaCl → Ca²⁺ + Cl⁻ i = 2
CaS → Ca²⁺ + S⁻² i = 2
Li₂S → 2Li⁺ + S⁻² i = 3
KBr → K⁺ + Br⁻ i = 2
AlCl₃ → Al³⁺ + 3Cl⁻ i = 4
MgC₂ → Mg²⁺ + 2C⁻ i = 3
KI → K⁺ + I⁻ i = 2
K₂S → 2K⁺ + S⁻² i = 3
The biggest i, is in pair D.
