The balanced equation for the above reaction is as follows;
3NO₂ + H₂O --> 2HNO₃ + NO
stoichiometry of NO₂ to NO is 3:1
molar volume is where 1 mol of any gas occupies a volume of 22.4 L
volume of gas is directly proportional to number of moles of gas.
therefore stoichiometry can be applied for volume as well.
volume ratio of NO₂ to NO is 3:1
volume of NO₂ reacted - 854 L
therefore volume of NO formed - 854 L /3 = 285 L
volume of NO formed - 285 L
According to markovnikov's rule of the electrophilic addition to an alkene, the electrophile, usually a proton, is more likely to add to the less-substituted carbon in a double bond.
With additional substituents present in this configuration, the intermediate carbocation is stabilised by being located on the more-substituted carbon.
The nucleophile will then end up in a double bond on the more-substituted carbon in a reaction that follows Markovnikov's rule.The outcome of some addition reactions is described by Markovnikov's rule or Markownikoff's rule in organic chemistry. Vladimir Markovnikov, a Russian scientist, created the rule in 1870.
To learn more about Markovnikov's rule
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