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Varvara68 [4.7K]
3 years ago
11

HELPPPPP!!

Chemistry
1 answer:
Lelechka [254]3 years ago
3 0

Answer:

D. 45.0 g

Explanation:

In present reaction, 1 mol of N2 react with 3 moles of H2 to generate 2 moles of NH3

Thus, 2 moles of NH3 ≡ 3 moles  of H2

Therefore, 15 moles of NH3 ≡ (3×15)/2 = 22.5 moles of H2.

We know that, 1 mole of H2 ≡ 2 g

Therefore, 22.5 moles of H2 ≡ 2 × 22.5 = 45 g

Thus, 45 g of hydrogen are needed to produce 15.0 mol of ammonia, if the reaction goes to completion

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Approximately 1.10\; {\rm V} under standard conditions.

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Write down the ionic equation for this reaction:

\begin{aligned}& {\rm Cu^{2+}}\, (aq) + 2\; {\rm Cl^{-}}\, (aq) + {\rm Zn}\, (s)\\ & \to {\rm Zn^{2+}} \, (aq) + 2\; {\rm Cl^{-}}\, (aq) + {\rm Cu}\, (s)\end{aligned}.

The net ionic equation for this reaction would be:

{\rm Cu^{2+}}\, (aq) + {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + {\rm Cu}\, (s).

In this reaction:

  • Zinc loses electrons and was oxidized (at the anode): {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}}.
  • Copper gains electrons and was reduced (at the cathode): {\rm Cu^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Cu} \, (s).

Look up the standard potentials for each half-reaction on a table of standard reduction potentials.

Notice that {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} is oxidation and is likely not on the table of standard reduction potentials. However, the reverse reaction, {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Zn}\, (s), is reduction and is likely on the table.

  • E(\text{anode}) = -0.7618\; {\rm V} for {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Zn}\, (s), and
  • E(\text{cathode}) = 0.3419\; {\rm V} for {\rm Cu^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Cu} \, (s).

The reduction potential of {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} would be -E(\text{anode}) = -(-0.7618\; {\rm V}) = 0.7618\; {\rm V}, the opposite of the reverse reaction {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Zn}\, (s).

The standard potential of the overall reaction would be the sum of the standard potentials of the two half-reactions:

\begin{aligned} E^{\circ} &= E^{\circ}(\text{cathode}) + (-E^{\circ}(\text{anode})) \\ &= 0.3419 - (-0.7618\; {\rm V}) \\ &\approx 1.10\; {\rm V}\end{aligned}.

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