2 answers:
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Answer: The time is 0.69/k seconds
Explanation:
The following integrated first order rate law
ln[SO₂Cl₂] - ln[SO₂Cl₂]₀ = - k×t
where
[SO₂Cl₂] concentration at time t,
[SO₂Cl₂]₀ initial concentration,
k rate constant
Therefore, the time elapsed after a certain concentration variation is given by:
We could assume that SO₂Cl₂ behaves as a ideal gas mixture so partial pressure is proportional to concentration:
In conclusion,
t = ln( p(SO₂Cl₂)₀/p(SO₂Cl₂) )/k
for
Answer:
Usually give off heat energy
Explanation:
Exergonic reactions are the ones which are spontaneous. Spontaneous reactions are indicated by the negative change in the Gibbs free energy. In order to provide characteristics for an exergonic reaction, we need to define the Gibbs free energy in terms of the enthalpy change and the entropy change:
Here:
is the enthalpy change;
is the entropy change;
is the absolute temperature.
In order to achieve a negative value in the Gibbs free energy change, we should have:
This is true for all temperatures if:
The major term here is the change in enthalpy, notice that we wish the enthalpy change to be negative.
Negative enthalpy change corresponds to an exothermic reaction, the one which releases heat. This means exergonic reactions would usually give off heat.