Answer:
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Explanation:
An electrochemical cell is a device capable of either generating electrical energy from chemical reactions or using electrical energy to cause chemical reactions.
See attachment for the step by step solution of the given problem.
The enthalpy change of the reaction when sodium hydroxide and sulfuric acid react can be calculated using the mass of solution, temperature change, and specific heat of water.
The balanced chemical equation for the reaction can be represented as,

Given volume of the solution = 101.2 mL + 50.6 mL = 151.8 mL
Heat of the reaction, q =
Δ
m is mass of the solution = 151.8 mL * 
C is the specific heat of solution = 4.18 
ΔT is the temperature change = 
q = 
Moles of NaOH =
NaOH
Moles of
= 
Enthalpy of the reaction = 
In order to calculate the number of atoms, we must first know the number of moles present. And
moles = (mass present) / (molecular mass)
Therefore, the moles of Mg present are
170 / 24 = 7.08
The number of atoms in a mole of substance is given by Avagadro's Number which is 6.02 x 10^23
Since there are 7.08 moles, there are:
7.08 * 6.02*10^23
= 4.26 * 10^24 atoms
The hydrocarbon is used in excess.
<h3><u>Explanation</u>:</h3>
The bromination of an arene is not simple as bromination of an alkane. This is because the carbocation or free radicle formation in benzene is a very energy consuming process. This is why a lewis base like aluminium bromide or ferric bromide is used. The ferric bromide takes in the bromine radicle and forms the brominium cation which helps in the formation of electrophile. Now this electrophile brominium cation attacks the benzene ring and forms a temporary sp3 hybrid carbon intermediate. Then the hydrogen is taken by the FeBr4- forming HBr and regenerating the FeBr3 as well as Aromaticity of the arene species at the same time. Here hydrocarbon is used in excess just to prevent the chances of multiple substitution in the same arene molecule.