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2 years ago

125 ml of nitrogen gas is collected at 70.0 degrees Celsius. The pressure

Chemistry

1 answer:

dybincka [34]2 years ago

5 0

Answer: Volume of the gas at STP is 22.53 L.

Explanation:

Given : Volume = 125 mL (as 1 mL = 0.001 L) = 0.125 L

Temperature = $70^{o}C = (70 + 273) K = 343 K$

Pressure = $125 kPa = 125 kPa \times \frac{0.01 atm}{1 kPa} = 1.25 atm$

According to the ideal gas equation, the volume of given nitrogen gas is calculated as follows.

PV = nRT

where,

P = pressure

V = volume

n = number of moles

R = gas constant = 0.0821 L atm/mol K

T = temperature

Substitute the values into above formula as follows.

$1.25 atm \times V = 1 mol \times 0.0821 L atm/mol K \times 343 K\\V = \frac{1 mol \times 0.0821 L atm/mol K \times 343 K}{1.25 atm}\\= \frac{28.1603}{1.25} L\\= 22.53 L$

Hence, volume of the gas at STP is 22.53 L.

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Which aqueous solution has the highest boiling point at standard pressure?(1) 1.0 M KC1(aq) (3) 2.0 M KCl(aq)(2) 1.0 M CaC12(aq)

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Adding solute to water elevates the boiling point.

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i is the van 't Hoff factor.

van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass. For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1.

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m is the molality of the solution.

(1) 1.0 M KCl(aq):

i for KCl = no. of particles produced when the substance is dissolved/no. of original particle = 2/1 = 2.

suppose molarity = molality, m = 1.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (2)(Kb)(1.0 m) = 2(Kb).

(2) 2.0 M KCl(aq):

i for KCl = no. of particles produced when the substance is dissolved/no. of original particle = 2/1 = 2.

suppose molarity = molality, m = 2.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (2)(Kb)(2.0 m) = 4(Kb).

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i for CaCl₂ = no. of particles produced when the substance is dissolved/no. of original particle = 3/1 = 3.

suppose molarity = molality, m = 1.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (3)(Kb)(1.0 m) = 3(Kb).

(4) 2.0 M CaCl₂(aq):

i for CaCl₂ = no. of particles produced when the substance is dissolved/no. of original particle = 3/1 = 3.

suppose molarity = molality, m = 2.0 m,

∴ ΔTb for (1.0 M KCl) = i.Kb.m = (3)(Kb)(2.0 m) = 6(Kb).

So, the aqueous solution has the highest boiling point at standard pressure is: (4) 2.0 M CaCl₂(aq).

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