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Tamiku [17]
3 years ago
7

In the Haber process for ammonia synthesis, K " 0.036 for N 2 (g) ! 3 H 2 (g) ∆ 2 NH 3 (g) at 500. K. If a 2.0-L reactor is char

ged with 1.42 bar of N 2 and 2.87 bar of H 2 , what will the equilibrium partial pressures in the mixture be?
Chemistry
1 answer:
lisabon 2012 [21]3 years ago
6 0

Answer : The partial pressure of N_2,H_2\text{ and }NH_3 at equilibrium are, 1.133, 2.009, 0.574 bar respectively. The total pressure at equilibrium is, 3.716 bar

Solution :  Given,

Initial pressure of N_2 = 1.42 bar

Initial pressure of H_2 = 2.87 bar

K_p = 0.036

The given equilibrium reaction is,

                              N_2(g)+H_2(g)\rightleftharpoons 2NH_3(g)

Initially                   1.42      2.87             0

At equilibrium    (1.42-x)  (2.87-3x)     2x

The expression of K_p will be,

K_p=\frac{(p_{NH_3})^2}{(p_{N_2})(p_{H_2})^3}

Now put all the values of partial pressure, we get

0.036=\frac{(2x)^2}{(1.42-x)\times (2.87-3x)^3}

By solving the term x, we get

x=0.287\text{ and }3.889

From the values of 'x' we conclude that, x = 3.889 can not more than initial partial pressures. So, the value of 'x' which is equal to 3.889 is not consider.

Thus, the partial pressure of NH_3 at equilibrium = 2x = 2 × 0.287 = 0.574 bar

The partial pressure of N_2 at equilibrium = (1.42-x) = (1.42-0.287) = 1.133 bar

The partial pressure of H_2 at equilibrium = (2.87-3x) = [2.87-3(0.287)] = 2.009 bar

The total pressure at equilibrium = Partial pressure of N_2 + Partial pressure of H_2 + Partial pressure of NH_3

The total pressure at equilibrium = 1.133 + 2.009 + 0.574 = 3.716 bar

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malfutka [58]

Answer:

[F^-]_{max}=4x10{-3}\frac{molF^-}{L}

Explanation:

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In this case, for the described situation, we infer that calcium reacts with fluoride ions to yield insoluble calcium fluoride as shown below:

Ca^{+2}(aq)+2F^-(aq)\rightleftharpoons CaF_2(s)

Which is typically an equilibrium reaction, since calcium fluoride is able to come back to the ions. In such a way, since the maximum amount is computed via stoichiometry, we can see a 1:2 mole ratio between the ions, therefore, the required maximum amount of fluoride ions in the "hard" water (assuming no other ions) turns out:

[F^-]_{max}=2.0x10^{-3}\frac{molCa^{2+}}{L}*\frac{2molF^-}{1molCa^{2+}}  \\

[F^-]_{max}=4x10{-3}\frac{molF^-}{L}

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What is the empirical formula of a compound containing 5.03 grams carbon, 0.42 grams hydrogen, and 44.5 grams chlorine?
djverab [1.8K]

The empirical formula of the compound is CHCl₃.

<h3>Calculation:</h3>

Given,

Mass of carbon = 5.03 g

Mass of hydrogen = 0.42 g

Mass of chlorine = 44.5 g

Molecular weight of carbon = 12 g

Molecular weight of hydrogen = 1 g

Molecular weight of chlorine = 35.4 g

First, calculate the moles of each element,

                      Moles = given mass/ molecular weight

Moles of carbon = 5.03/12 = 0.42

Moles of hydrogen = 0.42/1 = 0.42

Moles of chlorine = 44.5/ 35.4 = 1.26

Divide the moles of each element by the smallest number of moles,

0.42 mol of C/ 0.42 = 1 C

0.42 mol of H/ 0.42 = 1 H

1.26 mol of Cl/0.42 = 3 Cl

The ratio of elements is 1:1:3

Therefore the empirical formula of the compound will be CHCl₃.

Learn more about empirical formula here:

brainly.com/question/20708102

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5 0
2 years ago
The empirical formula of a compound is CH2O and its molecular weight is 90.09 g/mol. Determine the molecular formula.
Pachacha [2.7K]

Answer : The molecular formula of the compound will be, C_{3}H_{6}O_3

Explanation :

Empirical formula : It is the simplest form of the chemical formula which depicts the whole number of atoms of each element present in the compound.  

Molecular formula : it is the chemical formula which depicts the actual number of atoms of each element present in the compound.  

For determining the molecular formula, we need to determine the valency which is multiplied by each element to get the molecular formula.

The equation used to calculate the valency is :

n=\frac{\text{molecular mass}}{\text{empirical mass}}

As we are given that the empirical formula of a compound is CH_2O and the molar mass of compound is, 90.09 gram/mol.

The empirical mass of CH_2O = 1(12) + 2(1) + 1(16) = 30 g/eq

n=\frac{\text{molecular mass}}{\text{empirical mass}}

n=\frac{90.09}{30}=3

Molecular formula = (CH_2O)_n=(CH_2O)_3=C_{3}H_{6}O_3

Thus, the molecular formula of the compound will be, C_{3}H_{6}O_3

7 0
3 years ago
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