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GarryVolchara [31]
3 years ago
14

An unknown aqueous metal analysis yielded a detector response of 0.255. When 1.00 mL of a solution containing 100.0 ppm of the m

etal was mixed with 99.0 mL of the unknown, the detector signal increased to 0.502. Calculate the concentration of the metal in the unknown solution. Report your answer in ppm
Chemistry
1 answer:
AVprozaik [17]3 years ago
3 0

Answer:

1.022ppm is the unknown concentration of the metal

Explanation:

Based on Lambert-Beer law, the increasing in signal of a detector is directly proportional to its concentration.

The unknown concentration (X) produces a signal of 0.255

99mL * X + 1mL * 100ppm / 100mL produces a signal of 0.502

0.99X + 1ppm produce 0.502, thus, X is:

0.255 * (0.99X + 1 / 0.502) =

X = 0.503X + 0.508

0.497X = 0.508

X =

1.022ppm is the unknown concentration of the metal

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The first-order rearrangement of CH3NC is measured to have a rate constant of 3.61 x 10-15 s-1 at 298 K and a rate constant of 8
laiz [17]

Answer:

The correct answer is 160.37 KJ/mol.

Explanation:

To find the activation energy in the given case, there is a need to use the Arrhenius equation, which is,  

k = Ae^-Ea/RT

k1 = Ae^-Ea/RT1 and k2 = Ae^-Ea/RT2

k2/k1 = e^-Ea/R (1/T2-1/T1)

ln(k2/k1) = Ea/R (1/T1-1/T2)

The values of rate constant k1 and k2 are 3.61 * 10^-15 s^-1 and 8.66 * 10^-7 s^-1.  

The temperatures T1 and T2 are 298 K and 425 K respectively.  

Now by filling the values we get:  

ln (8.66*10^-7/3.61*10^-15) = Ea/R (1/298-1/425)

19.29 = Ea/R * 0.001

Ea = 160.37 KJ/mol

3 0
3 years ago
How many grams of oxygen are produced when 7.65 moles of water is decomposed
maksim [4K]

Answer:

The answer to your question is 122.4 g of O₂

Explanation:

Data

mass of O₂ = ?

moles of H₂O = 7.65

Process

1.- Write the balanced chemical reaction

                   2H₂O  ⇒  2H₂  +  O₂

2.- Convert the moles of H₂O to grams

molar mass of H₂O = 2 + 16 = 18 g

                    18 g of H₂O ---------------- 1 mol

                      x                ----------------- 7.65 moles

                      x = (7.65 x 18) / 1

                      x = 137.7 g H₂O

3.- Calculate the grams of O₂

                 36 g of H₂O -------------------- 32 g of O₂

              137.7 g of H₂O -------------------  x

                        x = (32 x 137.7) / 36

                       x = 122.4 g of O₂

 

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4 years ago
What is the formula for the compound formed by calcium ions and chloride ions? (1) CaCl (2) CaCl2 (3) CaCl3 (4) Ca2Cl
amid [387]
I think it would be c
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Which of the following isoelectronic series is correctly ranked from largest ionic radius to smallest ionic radius? 1. N 3−, O 2
love history [14]

Answer:

<u>Option 1</u>:  N⁻³ > O⁻² > F⁻ > Na⁺ > Mg⁺²    

Explanation:

<u>Ionic radius is the radius of an atom´s ion in ionic crystal structure</u>.<u> </u><u><em>In an ion that lose an electron, to form a cation, the radius of the ion gets smaller</em></u><em>, </em>because the repulsion between electrons decrease because fewer electrons are present. Conversely, <u><em>adding on electron to a neutral atom, to form an anion, causes electron - electron repulsions to increase, so the size of the radius of the ion gets bigger.</em></u>                  

<u><em>Isoelectronic species are ions or elements that have the same number of electrons in their electronic shells but have different overall charges, because of their different atomic numbers</em></u>.                        

<u><em>In a isolelectronic series (same number of electrons),</em></u> <u><em>the increase of the positive charge (given by the number of protons in the nucleus), will cause a decrease in radius </em></u>beacuse the greater electrostatic attraction between the electrons and the nucleus. Consequently, the ion with the greatest nuclear charge will have the smallest ionic radius and the ion with the smallest nulear charge will have the largest ionic radius.  

<u>We will use this principle to solve our problem</u>.  

In our case, the given ions are:  

  • N⁻³ :    Z = 7,  e⁻ = 10
  • O⁻²:     Z= 8,   e⁻ =10
  • F⁻:       Z = 9,  e⁻ = 10
  • Na⁺:    Z= 11,   e⁻ = 10
  • Mg⁺²:  Z=12,   e⁻ =10

where Z= number of protons, and e⁻ = number of electrons.

<em><u>Hence the decreasing order of ionic radius is:</u></em>

N⁻³ > O⁻² > F⁻ > Na⁺ > Mg⁺²  

Have a nice day!

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