The amount of gravitational potential energy acquired by the rock is equal to:

where
m is the mass of the rock
g is the gravitational acceleration

is the increase in height of the rock
Substituting the data of the problem, we find

So, Natalie gave 220.7 J of energy to the rock.
Exothermic is the answer to your question
1 Newton in Earth gravity is the equivalent weight of 1/9.80665 kg on Earth. This is derived using Newton's second law f=ma and assuming Earth gravity of 9.80665 m/s2. 1 N (Earth) = 0.101971621297793 kg.