Answer:
positive deviation from raoults law means when the vapour pressure is higher than the solution is expected to exhibit e.g of one is the mixture of acetone and ethanol
negative deviation means that it is opposed to the total vapour pressure of the solution
Answer:
Explanation:
general expression for the ionization energy of any one-electron species.
= z² x ground level energy / n²
z is atomic no , n is energy level .
ground level energy of
H = 1.31 x 10³ kJ/mol
He⁺ = 2² x 1.31 x 10³ kJ/mol = 5.24 x 10³ kJ/mol
Li²⁺ = 3² x 1.31 x 10³ kJ/mol = 1.18 x 10⁴ kJ/mol
b ) the ionization energy of B⁴⁺.
= 5² x 1.31 x 10³ kJ/mol = 32.75 x 10³ kJ/mol
c ) minimum energy required to remove the electron from the n = 3 level of He⁺ per mole
= 5.24 x 10³ / 9 kJ/mol
= 5.82 x 10² kJ/mol
= 5.82 x 10² x 10³ / 6.02 x 10²³ J
.9667 X 10⁻¹⁸ J
= .9667 X 10⁻¹⁸ / 1.6 X 10⁻¹⁹ eV
= 6.042 eV
= 1237.5 / 6.042
= 204.82 nm
=
d )
Answer: Option (A) is the correct answer.
Explanation:
In real gases, there exists force of attraction between the molecules at low temperature and high pressure. This is because at low temperature there occurs a decrease in kinetic energy of gas molecules and high pressure causes the molecules to come closer to each other.
As a result, forces of attraction increases as molecules come closer to each other and therefore, gases deviate from an ideal gas behavior.
And, at low pressure and high temperature there exists no force of attraction or repulsion between the molecules of a gas because they have high kinetic energy. Hence, gases behave ideally at these conditions.
Thus, we can conclude that the statement as the temperature approaches 0 K, the volume of the ideal gas will be larger than the volume of
because ideal gases lack inter-molecular forces, is true.