Yes the kingdom is more specific
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According to the question, the determined melting point of the compound is 112.5-113.0oC. When the solidified compound was retried, the melting point was found to be 133.6-154.5oC. This greater range higher than 112°C is caused by reusing samples leads to errors.
A pure sample is known by its sharp melting point. A pure sample does not melt over a large range. We can see this in the predetermined melting points of the pure sample(112.5-113.0oC).
However, reusing a sample introduces errors because the pure sample may become contaminated leading to a larger and higher range of melting point (133.6-154.5oC) which is far above 112°C.
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Nickel contains more atoms.
<u>Explanation:</u>
Number of atoms is determined by the Avogadro number.
1 mole of substance contains 6.022 X 10²³ atoms.
Given:
Mass of Nickel, Ni = 3.89g
Molecular weight of Ni = 58.6934g
Number of moles of Ni = 3.89/58.6934g
Number of atoms of Ni = 
Number of atoms of Ni = 0.39 X 10²³
Mass of silver, Ag = 6.61g
Molecular weight of Ag = 107.8682g
Number of moles of Ag = 6.61/107.8682
Number of atoms of Ag = 
Number of atoms of Ag = 0.36 X 10²³
Therefore, Nickel contains for atoms.