Answer:
The options <u>(A) -</u>The rate law for a given reaction can be determined from a knowledge of the rate-determining step in that reaction's mechanism. and <u>(C) </u>-The rate laws of bimolecular elementary reactions are second order overall ,<u>is true.</u>
Explanation:
(A) -The rate law can only be calculated from the reaction's slowest or rate-determining phase, according to the first sentence.
(B) -The second statement is not entirely right, since we cannot evaluate an accurate rate law by simply looking at the net equation. It must be decided by experimentation.
(C) -Since there are two reactants, the third statement is correct: most bimolecular reactions are second order overall.
(D)-The fourth argument is incorrect. We must track the rates of and elementary phase that is following the reaction in order to determine the rate.
<u>Therefore , the first and third statement is true.</u>
One mole of a substance is defined by Avogadro as consisting of 6.022 x 1023 atoms. This is Avogadro's number. To calculate the number of atoms in two moles of sodium, use dimensional analysis. 2.0 moles Na x 6.022⋅1023g1mol=1.20⋅1024 atoms of Na
Balanced Eqn
2
C
2
H
6
+
7
O
2
=
4
C
O
2
+
6
H
2
O
By the Balanced eqn
60g ethane requires 7x32= 224g oxygen
here ethane is in excess.oxygen will be fully consumed
hence
300g oxygen will consume
60
⋅
300
224
=
80.36
g
ethane
leaving (270-80.36)= 189.64 g ethane.
By the Balanced eqn
60g ethane produces 4x44 g CO2
hence amount of CO2 produced =
4
⋅
44
⋅
80.36
60
=
235.72
g
and its no. of moles will be
235.72
44
=5.36 where 44 is the molar mass of Carbon dioxide
hope this helps
