HBr and HF are both monoprotic Arrhenius acids—that is, in aqueous solution, they dissociate and ionize to give hydrogen ions. A strong acid ionizes completely; a weak acid ionizes partially.
In this case, HBr, being a strong acid, would ionize completely in water to yield H+ and Br- ions. However, HF, being a weak acid, would ionize only to a limited extent: some of the HF molecules will ionize into H+ and F- ions, but most of the HF will remain undissociated.
pH is, by definition, a measurement of the concentration of hydrogen ions in solution (pH = -log[H+]). A higher concentration of hydrogen ions gives a lower pH, while a lower concentration of hydrogen ions gives a higher pH. At 25 °C, a pH of 7 indicates a neutral solution; a pH less than 7 indicates an acidic solution; and a pH greater than 7 indicates a basic solution.
If we have equal concentrations of HBr and HF, then the HBr solution will have a greater concentration of hydrogen ions in solution than the HF solution. Consequently, the pH of the HBr solution will be less than the pH of the HF solution.
Choice A is incorrect: Strong acids like HBr dissociate completely, not partially.
Choice B is incorrect: While the initial concentration of HBr and HF are the same, the H+ concentration in the HBr solution is greater. Since pH is a function of H+ concentration, the pH of the two solutions cannot be the same.
Choice C is correct: A greater H+ concentration gives a lower pH value. The HBr solution has the greater H+ concentration. Thus, the pH of the HBr solution would be less than that of the HF solution.
Choice D is incorrect for the reason why choice C is correct.
<span>homogeneous because particles are mixed uniformly</span>
The given sentence is part of a longer question.
I found this question with the same sentence. So, I will help you using this question:
For the reaction N2O4<span>(g) ⇄ 2NO</span>2(g), a reaction mixture at a certain temperature initially contains both N2O4 and NO2 in their standard states (meaning they are gases with a pressure of 1 atm<span>). If </span>Kp = 0.15, which statement is true of the reaction mixture before
any reaction occurs?
(a) Q = K<span>; The reaction </span>is at equilibrium.
(b) Q < K<span>;
The reaction </span>will proceed to
the right.
(c) Q > K<span>; The reaction </span>will proceed to the left.
The answer is the option (c) Q > K<span>; The reaction will proceed to the </span>left,
since Qp<span> = </span>1<span>, and 1 > 0.15.</span>
Explanation:
Kp is the equilibrium constant in term of the partial pressures of the gases.
Q is the reaction quotient. It is a measure of the progress of a chemical reaction.
The reaction quotient has the same form of the equilibrium constant but using the concentrations or partial pressures at any moment.
At equilibrium both Kp and Q are equal. Q = Kp
If Q < Kp then the reaction will go to the right (forward reaction) trying to reach the equilibrium,
If Q > Kp then the reaction will go to the left (reverse reaction) trying to reach the equilibrium.
Here, the state is that both pressures are 1 atm, so Q = (1)^2 / 1 = 1.
Since, Q = 1 and Kp = 0.15, Q > Kp and the reaction will proceed to the left.
