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Nitella [24]
3 years ago
6

Prepare 15 mg/dl working standard solution from a stock solution of 20 mg/dl. State the volume of diluent and dilution.

Chemistry
1 answer:
Anastasy [175]3 years ago
4 0

Preparing 15 mg/gl working standard solution from a 20 mg/dl stock solution will require the application of the dilution principle.

Recalling the principle:

initial volume x initial molarity = final volume x final molarity

Since we were not given any volume to work with, we can as well just take an arbitrary volume to be prepared. Let's assume that the stock solution is 10 mL and we want to prepare 15 mg/gl from it:

Applying the dilution principle:

10 x 20 = final volume x 15

final volume = 200/15

                       = 13.33 mL

This means that in order to prepare 13.33 mL, 15 mg/l working standard solution from 10 ml, 20 mg/dl stock solution, 3.33 mL of the diluent must be added to the stock solution.

More on dilution principle can be found here: brainly.com/question/11493179

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The thallium (present as Tl2SO4) in a 9.486-g pesticide sample was precipitated as thallium(I) iodide. Calculate the mass percen
tino4ka555 [31]

Answer: The mass percentage of Tl_2SO_4 is 5.86%

Explanation:

To calculate the mass percentage of Tl_2SO_4 in the sample it is necessary to know the mass of the solute (Tl_2SO_4 in this case), and the mass of the solution (pesticide sample, whose mass is explicit in the letter of the problem).

To calculate the mass of the solute, we must take the mass of the TlI precipitate.  We can establish a relation between the mass of TlI and Tl_2SO_4 using the stoichiometry of the compounds:

moles\ of\ TlI = \frac{0.1824 g}{331.27\frac{g}{mol} } = 5.51*10^{-4}\ mol.

Since for every mole of Tl in TlI there are two moles of Tl in Tl_2SO_4, we have:

moles\ of\ Tl_2SO_4 = 2 * moles\ of\ TlI = 1,102*10^{-3}\ mol

Using the molar mass of Tl_2SO_4 we have:

mass\ of\ Tl_2SO_4 = 1,102*10^{-3}\ mol * 504.83\ \frac{g}{mol}= 0.56\ g

Finally, we can use the mass percentage formula:

mass\ percentage = (\frac{solute\ mass}{solution\ mass} )*100 = (\frac{mass\ of\ Tl_2SO_4}{pesticide\ sample\ mass})*100 = (\frac{0.56g}{9.486g})*100 = 5.86\%

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2 years ago
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Jobisdone [24]

Answer:

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