Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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Answer:
Molecular formula for the gas is: C₄H₁₀
Explanation:
Let's propose the Ideal Gases Law to determine the moles of gas, that contains 0.087 g
At STP → 1 atm and 273.15K
1 atm . 0.0336 L = n . 0.082 . 273.15 K
n = (1 atm . 0.0336 L) / (0.082 . 273.15 K)
n = 1.500 × 10⁻³ moles
Molar mass of gas = 0.087 g / 1.500 × 10⁻³ moles = 58 g/m
Now we propose rules of three:
If 0.580 g of gas has ____ 0.480 g of C _____ 0.100 g of C
58 g of gas (1mol) would have:
(58 g . 0.480) / 0.580 = 48 g of C
(58 g . 0.100) / 0.580 = 10 g of H
48 g of C / 12 g/mol = 4 mol
10 g of H / 1g/mol = 10 moles
