<span>Nitrogen gas is converted to nitrate compounds by nitrogen-fixing bacteria in soil turns nitrogen gas into root nodules. Nitrogen is the most commonly limiting nutrient in plants. Legumes use nitrogen fixing bacteria, specifically symbiotic rhizobia bacteria, within their root nodules to counter the limitation.</span>
Since there are 23 days and 24 hours in each day, you multi-ply them and get 552 hours. Since each hours is 60 minutes, 552*60 is 33120 minutes. Since one minute is 60 seconds, 60*33120 is 1,987,200 seconds. Therefore, there are 1,987,200 seconds in 23 days.
Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.
Discussion:
1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.
2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.
3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.
4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.
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