Answer:
5.7
Explanation:
(C₂H₅)₃NHCl dissociates according to the following equation.
(C₂H₅)₃NHCl ⇒ (C₂H₅)₃NH⁺ + Cl⁻
The molar ratio of (C₂H₅)₃NHCl to (C₂H₅)₃NH⁺ is 1:1. Then, the concentration of (C₂H₅)₃NH⁺ is Ca = 0.166 M.
(C₂H₅)₃NH⁺ is the conjugate acid of (C₂H₅)₃N. Given the Kb of (C₂H₅)₃N, we can calculate Ka for (C₂H₅)₃NH⁺ using the following expression.
Ka × Kb = Kw
Ka = Kw / Kb
Ka = 1.0 × 10⁻¹⁴ / 5.2 × 10⁻⁴
Ka = 1.9 × 10⁻¹¹
(C₂H₅)₃NH⁺ dissociates according to the following equation.
(C₂H₅)₃NH⁺ ⇄ (C₂H₅)₃N + H⁺
We can calculate [H⁺] using the following expression.
[H⁺] = √(Ca × Ka) = √(0.166 × 1.9 × 10⁻¹¹) = 1.8 × 10⁻⁶
The pH is:
pH = -log [H⁺] = -log 1.8 × 10⁻⁶ = 5.7
Hi! where are the options?
Answer:
In the case of Mount Pinatubo, the result was a measurable cooling of the Earth's surface for a period of almost two years. Because they scatter and absorb incoming sunlight, aerosol particles exert a cooling effect on the Earth's surface.
Explanation:
Particles in a liquid move freely and liquids have a definite volume and indefinite shape since it occupies the shape of the container in which the liquid is in.
write an equation to represent the oxidation of an alcohol.
identify the reagents that may be used to oxidize a given alcohol.
identify the specific reagent that is used to oxidize primary alcohols to aldehydes rather than to carboxylic acids.
identify the product formed from the oxidation of a given alcohol with a specified oxidizing agent.
identify the alcohol needed to prepare a given aldehyde, ketone or carboxylic acid by simple oxidation.
write a mechanism for the oxidation of an alcohol using a chromium(VI) reagent.
The reading mentions that pyridinium chlorochromate (PCC) is a milder version of chromic acid that is suitable for converting a primary alcohol into an aldehyde without oxidizing it all the way to a carboxylic acid. This reagent is being replaced in laboratories by Dess‑Martin periodinane (DMP), which has several practical advantages over PCC, such as producing higher yields and requiring less rigorous reaction conditions. DMP is named after Daniel Dess and James Martin, who developed it in 1983.
This page looks at the oxidation of alcohols using acidified sodium or potassium dichromate(VI) solution. This reaction is used to make aldehydes, ketones and carboxylic acids, and as a way of distinguishing between primary, secondary and tertiary alcohols.
Oxidizing the different types of alcohols
The oxidizing agent used in these reactions is normally a solution of sodium or potassium dichromate(VI) acidified with dilute sulfuric acid. If oxidation occurs, the orange solution containing the dichromate(VI) ions is reduced to a green solution containing chromium(III) ions. The electron-half-equation for this reaction is
Cr2O2−7+14H++6e−→2Cr3++7H2O
