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OLga [1]
2 years ago
12

A shipment from Earth to Mars contains a 60 gallon​ [gal] tank filled with an ideal gas. The molecular weight of the ideal gas i

s 15.9 grams per mole​ [g/mol]. NASA tells the astronauts on Mars that the tank and gas combined had an initial total mass of 5 kilograms​ [kg] and the pressure was 3 atmospheres​ [atm] before it left the Earth. During the​ trip, the temperature was kept constant at 20 degrees Celsius ​[°​C]. When it arrives on​ Mars, the astronauts check the sensors and discover the pressure is 2.2 atmospheres​ [atm] and the temperature is 20 degrees Celsius ​[°​C]. Based on this​ information, the astronauts determine that some of the gas leaked during shipment. Determine how much gas leaked from the tank in units of grams​ [g]. Gravity on Mars​ = 3.71 meters per second squared ​[m/s2​].
Engineering
1 answer:
mylen [45]2 years ago
3 0

The ideal gas equation can find the amount of gas lost is 7 mol

Given parameters

  • The initial and final pressures P1 = 3 atm and P2 = 2.2 atm
  • The temperature T = 20ºC
  • Container volume V = 60 gallon

To find

  • The moles of gas lost

The intentional system of measurements (SI) is a system that determines which are the fundamental units, this allows to carry out calculations and exchange measurements in a uniform way and without errors, let's reduce the magnitudes to the SI system

        P₁ = 3 atm (1 10⁵ Pa / 1 atm) = 3 10⁵ Pa

        P₂ = 2.2 atm (1 10⁵ / 1 atm) = 2.2 10⁵ Pa

        PM = 15.9 g / mol (1 kg / 1000 g) = 15.9 10⁻⁻³ kg / mol

        V = 60 gallon (1 m³ / 264.172 gal) = 0.2271 m³

         T = 20 + 273.15 = 293.15 K

Ideal gases are gases that have no interactions between them, so they can be described by the equation

          PV = n R T

Where P is the pressure, V the volume, n the number of moles, R the ideal gas constant (R = 8.314 \frac{J}{mol \ K}) and T the temperature.

Let's look for the initial moles, that is, on Earth

          n = \frac{PV}{RT}

          n = \frac{3 \ 10^5  \ 0.2271 }{ 8.314 \ 293.15}

          n = 27.95 mol

Let's write the ideal gas equation for the two instants let's use subscript 1 for Earth and subscript 2 when the spacecraft is on Tuesday

            P₁ V = n₁ R T

             P₂ V = n₂ R T

            \frac{P_1}{n_1} = \frac{P_2}{n_2}

            n₂ = \frac{P_2}{P_1} \ n_1  

            n₂ = \frac{2.2 \ 10^5 }{ 3 \ 10^5} \ 27.95

            n₂ = 20.95 mol

This is the amount of moles left, the moles lost are

           n_ {lost} = n₁ -n₂

           n_ {lost} = 27.95 - 20.95

           n_ {lost} = 7 mol

Using the ideal gas equation we can find the amount of gas lost is 7 mol

Learn more about ideal gas here:

brainly.com/question/6684527

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Tensile Strength (MPa) Number-Average Molecular Weight (g/mol)
IceJOKER [234]

Answer:

\mathbf{T_{S \infty } \ \approx 215.481 \ MPa}

\mathbf{M_n = 49163.56431  \ g/mol }

Explanation:

The question can be well structured in a table format as illustrated below:

Tensile Strength (MPa)            Number- Average Molecular Weight  (g/mol)

82                                                  12,700

156                                                 28,500

The tensile strength and number-average molecular weight for two polyethylene materials given above.

Estimate the number-average molecular weight that is required to give a tensile strength required above. Using the data given find TS (infinity) in MPa.

<u>SOLUTION:</u>

We know that :

T_S = T_{S \infty} - \dfrac{A}{M_n}

where;

T_S = Tensile Strength

T_{S \infty} = Tensile Strength (Infinity)

M_n = Number- Average Molecular Weight  (g/mol)

SO;

82= T_{S \infty} - \dfrac{A}{12700} ---- (1)

156= T_{S \infty} - \dfrac{A}{28500} ---- (2)

From equation (1) ; collecting the like terms; we have :

T_{S \infty} =82+ \dfrac{A}{12700}

From equation (2) ; we have:

T_{S \infty} =156+ \dfrac{A}{28500}

So; T_{S \infty} = T_{S \infty}

Then;

T_{S \infty} =82+ \dfrac{A}{12700} =156+ \dfrac{A}{28500}

Solving by L.C.M

\dfrac{82(12700) + A}{12700} =\dfrac{156(28500) + A}{28500}

\dfrac{1041400 + A}{12700} =\dfrac{4446000 + A}{28500}

By cross multiplying ; we have:

({4446000 + A})*  {12700} ={28500} *({1041400 + A})

(5.64642*10^{10} + 12700A) =(2.96799*10^{10}+ 28500A)

Collecting like terms ; we have

(5.64642*10^{10} - 2.96799*10^{10} ) =( 28500A- 12700A)

2.67843*10^{10}  = 15800 \ A

Dividing both sides by 15800:

\dfrac{ 2.67843*10^{10} }{15800} =\dfrac{15800 \ A}{15800}

A = 1695208.861

From equation (1);

82= T_{S \infty} - \dfrac{A}{12700} ---- (1)

Replacing A = 1695208.861 in the above equation; we have:

82= T_{S \infty} - \dfrac{1695208.861}{12700}

T_{S \infty}= 82 + \dfrac{1695208.861}{12700}

T_{S \infty}= \dfrac{82(12700) +1695208.861 }{12700}

T_{S \infty}= \dfrac{1041400 +1695208.861 }{12700}

T_{S \infty}= \dfrac{2736608.861 }{12700}

\mathbf{T_{S \infty } \ \approx 215.481 \ MPa}

From equation(2);

156= T_{S \infty} - \dfrac{A}{28500} ---- (2)

Replacing A = 1695208.861 in the above equation; we have:

156= T_{S \infty} - \dfrac{1695208.861}{28500}

T_{S \infty}= 156 + \dfrac{1695208.861}{28500}

T_{S \infty}= \dfrac{156(28500) +1695208.861 }{28500}

T_{S \infty}= \dfrac{4446000 +1695208.861 }{28500}

T_{S \infty}= \dfrac{6141208.861}{28500}

\mathbf{T_{S \infty } \ \approx 215.481 \ MPa}

We are to also estimate the number- average molecular weight that is required to give a tensile strength required above.

If the Tensile Strength (MPa) is 82 MPa

Definitely the average molecular weight will be = 12,700 g/mol

If the Tensile Strength (MPa) is 156 MPa

Definitely the average molecular weight will be = 28,500 g/mol

But;

Let us assume that the Tensile Strength (MPa) = 181 MPa for example.

Using the same formula:

T_S = T_{S \infty} - \dfrac{A}{M_n}

Then:

181 = 215.481- \dfrac{1695208.861 }{M_n}

Collecting like terms ; we have:

\dfrac{1695208.861 }{M_n} = 215.481-  181

\dfrac{1695208.861 }{M_n} =34.481

1695208.861= 34.481 M_n

Dividing both sides by 34.481; we have:

M_n = \dfrac{1695208.861}{34.481}

\mathbf{M_n = 49163.56431  \ g/mol }

5 0
3 years ago
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MrRa [10]
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3 years ago
A hot air balloon is used as an air-vehicle to carry passengers. It is assumed that this balloon is sealed and has a spherical s
monitta

Answer:

a. \dfrac{D_{1}}{ D_{2}}  =  \left (\dfrac{   \left{D_1}  }{ {D_2}}   \right )^{-3\times n} which is constant therefore, n = constant

b. The temperature at the end of the process is 109.6°C

c. The work done by the balloon boundaries = 10.81 MJ

The work done on the surrounding atmospheric air = 10.6 MJ

Explanation:

p₁ = 100 kPa

T₁ = 27°C

D₁ = 10 m

v₂ = 1.2 × v₁

p ∝ α·D

α = Constant

v_1 = \dfrac{4}{3} \times  \pi \times r^3

\therefore v_1 = \dfrac{4}{3} \times  \pi \times  \left (\dfrac{10}{2}  \right )^3 = 523.6 \ m^3

v₂ = 1.2 × v₁ = 1.2 × 523.6 = 628.32 m³

Therefore, D₂ = 10.63 m

We check the following relation for a polytropic process;

\dfrac{p_{1}}{p_{2}} = \left (\dfrac{V_{2}}{V_{1}}   \right )^{n} = \left (\dfrac{T_{1}}{T_{2}}   \right )^{\dfrac{n}{n-1}}

We have;

\dfrac{\alpha \times D_{1}}{\alpha \times D_{2}} = \left (\dfrac{ \dfrac{4}{3} \times  \pi \times  \left (\dfrac{D_2}{2}  \right )^3}{\dfrac{4}{3} \times  \pi \times  \left (\dfrac{D_1}{2}  \right )^3}   \right )^{n} = \left (\dfrac{   \left{D_2}  ^3}{ {D_1}^3}   \right )^{n}

\dfrac{D_{1}}{ D_{2}} = \left (\dfrac{   \left{D_2}  }{ {D_1}}   \right )^{3\times n} =  \left (\dfrac{   \left{D_1}  }{ {D_2}}   \right )^{-3\times n}

\dfrac{ D_{1}}{ D_{2}} = \left ( 1.2  \right )^{n} = \left (\dfrac{   \left{D_2}  ^3}{ {D_1}^3}   \right )^{n}

log  \left (\dfrac{D_{1}}{ D_{2}}\right )  =  -3\times n \times log\left (\dfrac{   \left{D_1}  }{ {D_2}}   \right )

n = -1/3

Therefore, the relation, pVⁿ = Constant

b. The temperature T₂ is found as follows;

\left (\dfrac{628.32 }{523.6}   \right )^{-\dfrac{1}{3} } = \left (\dfrac{300.15}{T_{2}}   \right )^{\dfrac{-\dfrac{1}{3}}{-\dfrac{1}{3}-1}} = \left (\dfrac{300.15}{T_{2}}   \right )^{\dfrac{1}{4}}

T₂ = 300.15/0.784 = 382.75 K = 109.6°C

c. W_{pdv} = \dfrac{p_1 \times v_1 -p_2 \times v_2 }{n-1}

p_2 = \dfrac{p_{1}}{ \left (\dfrac{V_{2}}{V_{1}}   \right )^{n} } =  \dfrac{100\times 10^3}{ \left (1.2) \right  ^{-\dfrac{1}{3} } }

p₂ =  100000/0.941 = 106.265 kPa

W_{pdv} = \dfrac{100 \times 10^3 \times 523.6 -106.265 \times 10^3  \times 628.32 }{-\dfrac{1}{3} -1} = 10806697.1433 \ J

The work done by the balloon boundaries = 10.81 MJ

Work done against atmospheric pressure, Pₐ, is given by the relation;

Pₐ × (V₂ - V₁) = 1.01×10⁵×(628.32 - 523.6) = 10576695.3 J

The work done on the surrounding atmospheric air = 10.6 MJ

4 0
3 years ago
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