It's only a small difference (103 degrees versus 104 degrees in water),
and I believe the usual rationalization is that since F is more
electronegative than H, the electrons in the O-F bond spend more time
away from the O (and close to the F) than the electrons in the O-H bond.
That shifts the effective center of the repulsive force between the
bonding pairs away from the O, and hence away from each other. So the
repulsion between the bonding pairs is slightly less, while the
repulsion between the lone pairs on the O is the same -- the result is
the angle between the bonds is a little less.
Hope this helps!
The quantity of heat absorbed is 33.4 kJ.
Δ<em>H</em>_fus = 334 J·g⁻¹
<em>q = m</em>Δ<em>H</em>_fus = 100.0 g × 334 J·g⁻¹ = 3.34 × 10⁴ J = 33.4 kJ
Answer:
Explanation: When solutions of potassium iodide and lead nitrate are combined?
The lead nitrate solution contains particles (ions) of lead, and the potassium iodide solution contains particles of iodide. When the solutions mix, the lead particles and iodide particles combine and create two new compounds, a yellow solid called lead iodide and a white solid called potassium nitrate. Chemical Equation Balancer Pb(NO3)2 + KI = KNO3 + PbI2. Potassium iodide and lead(II) nitrate are combined and undergo a double replacement reaction. Potassium iodide reacts with lead(II) nitrate and produces lead(II) iodide and potassium nitrate. Potassium nitrate is water soluble. The reaction is an example of a metathesis reaction, which involves the exchange of ions between the Pb(NO3)2 and KI. The Pb+2 ends up going after the I- resulting in the formation of PbI2, and the K+ ends up combining with the NO3- forming KNO3. NO3- All nitrates are soluble. ... (Many acid phosphates are soluble.)
