Answer:
CN^- is a strong field ligand
Explanation:
The complex, hexacyanoferrate II is an Fe^2+ specie. Fe^2+ is a d^6 specie. It may exist as high spin (paramagnetic) or low spin (diamagnetic) depending on the ligand. The energy of the d-orbitals become nondegenerate upon approach of a ligand. The extent of separation of the two orbitals and the energy between them is defined as the magnitude of crystal field splitting (∆o).
Ligands that cause a large crystal field splitting such as CN^- are called strong field ligands. They lead to the formation of diamagnetic species. Strong field ligands occur towards the end of the spectrochemical series of ligands.
Hence the complex, Fe(CN)6 4− is diamagnetic because the cyanide ion is a strong field ligand that causes the six d-electrons present to pair up in a low spin arrangement.
The amount of matter in an object is its Mass...
Answer:
Option A:
Zn(s) + Cu^(2+) (aq) → Cu(s) + Zn^(2+)(aq)
Explanation:
The half reactions given are:
Zn(s) → Zn^(2+)(aq) + 2e^(-)
Cu^(2+) (aq) + 2e^(-) → Cu(s)
From the given half reactions, we can see that in the first one, Zn undergoes oxidation to produce Zn^(2+).
While in the second half reaction, Cu^(2+) is reduced to Cu.
Thus, for the overall reaction, we will add both half reactions to get;
Zn(s) + Cu^(2+) (aq) + 2e^(-) → Cu(s) + Zn^(2+)(aq) + 2e^(-)
2e^(-) will cancel out to give us;
Zn(s) + Cu^(2+) (aq) → Cu(s) + Zn^(2+)(aq)
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Answer:
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