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3 years ago

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How to calculate precision chemistry.

1 answer:

chubhunter [2.5K]3 years ago

7 0

Answer:

Subtract The <u>mean</u> from each Numbers Given

Hope it helpz!

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Given the following heats of combustion. CH3OH(l) + 3/2 O2(g) CO2(g) + 2 H2O(l) ΔH°rxn = -726.4 kJ C(graphite) + O2(g) CO2(g) ΔH

sergeinik [125]

Answer:

The standard enthalpy of formation of methanol is, -238.7 kJ/mole

Explanation:

The formation reaction of CH_3OH will be,

$C(s)+2H_2(g)+\frac{1}{2}O_2\rightarrow CH_3OH(g),\Delta H_{formation}=?$

The intermediate balanced chemical reaction will be,

$C(graphite)+O_2(g)\rightarrow CO_2(g), \Delta H_1=-393.5kJ/mole$ ..[1]

$H_2(g)+\frac{1}{2}O_2(g)\rightarrow H_2O(l), \Delta H_2=-285.8kJ/mole$ ..[2]

$CH_3OH(g)+\frac{3}{2}O_2(g)\rightarrow CO_2(g)+2H_2O(l) , \Delta H_3=-726.4kJ/mole$ ..[3]

Now we will reverse the reaction 3, multiply reaction 2 by 2 then adding all the equations, Using Hess's law:

We get :

$C(graphite)+O_2(g)\rightarrow CO_2(g) , \Delta H_1=-393.5kJ/mole$ ..[1]

$2H_2(g)+2O_2(g)\rightarrow 2H_2O(l) ,\Delta H_2=2\times (-285.8kJ/mole)=-571.6kJ/mol$ ..[2]

$CO_2(g)+2H_2O(l)\rightarrow CH_3OH(g)+\frac{3}{2}O_2(g) ,\Delta H_3=726.4kJ/mole$ [3]

The expression for enthalpy of formation of $C_2H_4$ will be,

$\Delta H_{formation}=\Delta H_1+2\times \Delta H_2+\Delta H_3$

$\Delta H=(-393.5kJ/mole)+(-571.6kJ/mole)+(726.4kJ/mole)$

$\Delta H=-238.7kJ/mole$

The standard enthalpy of formation of methanol is, -238.7 kJ/mole

4 0

3 years ago

Jimmy mixes 2 chemicals in the lab. The chemicals change color and they get hot. The rise in temperature

gladu [14]

Answer:

A chemical reaction.

Explanation:

A change in temperature is evidence of a chemical reaction.

Also: They are chemicals...

3 0

3 years ago

Is trimming a bush because it grows too tall a chemical or physical change

professor190 [17]

Answer:

Physical Change

Explanation:

The bush is changing shapes, not changing what it is.

8 0

3 years ago

Calculate the ph of a dilute solution that contains a molar ratio of potassium acetate to acetic acid (pka ???? 4.76) of (a) 2:1

givi [52]

According to Hasselbach-Henderson equation:

$pH=pK_{a}+log\frac{[A^{-}]}{[HA]}$

Here, $[A^{-}]$ is concentration of conjugate base and [HA] is concentration of acid.

In the given problem, conjugate base is $CH_{3}COOK$ and acid is $CH_{3}COOH$ thus, Hasselbach-Henderson equation will be as follows:

$pH=pK_{a}+log\frac{[CH_{3}COOK]}{[CH_{3}COOH]}$ ...... (1)

(a) Ratio of concentration of potassium acetate and acetic acid is 2:1 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=2$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{2}{1}=5.06$

Therefore, pH of solution is 5.06.

(b) Ratio of concentration of potassium acetate and acetic acid is 1:3 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=\frac{1}{3}$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{1}{3}=4.28$

Therefore, pH of solution is 4.28.

(c)Ratio of concentration of potassium acetate and acetic acid is 5:1 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=\frac{5}{1}$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{5}{1}=5.45$

Therefore, pH of solution is 5.45.

(d) Ratio of concentration of potassium acetate and acetic acid is 1:1 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=1$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{1}{1}=4.76$

Therefore, pH of solution is 4.76.

(e) Ratio of concentration of potassium acetate and acetic acid is 1:10 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=\frac{1}{10}$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{1}{10}=3.76$

Therefore, pH of solution is 3.76.

4 0

3 years ago

Transpiration meaning and examples

FinnZ [79.3K]

Explanation:

Transpiration is the movement of water through plants using the xylem and also their loss from plants surfaces.

Water is a lost from plants from the leaves and the stomata. This water is usually replaced by the absorption of water by the root.

Transpiration is an important part of the water cycle in the biosphere.
Significant amount of water is lost from plant in the process of transpiration.
Transpiration water condenses in the atmosphere to form rain clouds.

An example of transpiration when water loses water from their leaves.

7 0

3 years ago