Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp = 
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104
+
- 200 = 0
Resolving the second degree equation:
=
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are
= 98.7 MPa and P(N₂O₄) = 101.3 MPa
Answer :
The time taken by the reaction is 19.2 seconds.
The order of reaction is, second order reaction.
Explanation :
The general formula to determine the unit of rate constant is:

Unit of rate constant Order of reaction
0
1
2
As the unit of rate constant is
. So, the order of reaction is second order.
The expression used for second order kinetics is:
![kt=\frac{1}{[A_t]}-\frac{1}{[A_o]}](https://tex.z-dn.net/?f=kt%3D%5Cfrac%7B1%7D%7B%5BA_t%5D%7D-%5Cfrac%7B1%7D%7B%5BA_o%5D%7D)
where,
k = rate constant = 
t = time = ?
= final concentration = 0.97 M
= initial concentration = 2.48 M
Now put all the given values in the above expression, we get:


Therefore, the time taken by the reaction is 19.2 seconds.
The answer for the following problem is mentioned below.
- <u><em>Therefore 298.44 grams of mercuric oxide is needed to produce 0.692 moles of oxygen molecule </em></u>
Explanation:
Given:
no of moles of the oxygen gas = 0.692
Also given:
2 HgO → 2 Hg + 
where,
HgO represents mercuric oxide
Hg represents mercury
represents oxygen
To calculate:
Molar mass of HgO:
Molar mass of HgO = 216 grams
molar mass of mercury (Hg) = 200 grams
molar mass of oxygen (O) =16 grams
HgO = 200 +16 = 216 grams
We know;
2×216 grams of HgO → 1 mole of oxygen molecule
? → 0.692 moles of oxygen molecule
= 
= 298.944 grams of HgO
<u><em>Therefore 298.44 grams of mercuric oxide is needed to produce 0.692 moles of oxygen molecule </em></u>
<u />
They can change properties completely
They can be separated
They form a new set of elements and compounds
<span>The elements become part of the original compounds</span>
Answer:
Decreased
Explanation:
You're faster when you go downhill than you are uphill.