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I believe the answer is the third option. Hope this helps! Please tell me if I am wrong or if there was an error in my answer... also sorry this answer is late.
Answer:
1) Endothermic.
2)
3)
Explanation:
Hello there!
1) In this case, for these calorimetry problems, we can realize that since the temperature decreases the reaction is endothermic because it is absorbing heat from the solution, that is why the temperature goes from 22.00 °C to 16.0°C.
2) Now, for the total heat released by the reaction, we first need to assume that all of it is released by the solution since it is possible to assume that the calorimeter is perfectly isolated. In such a way, it is also valid to assume that the specific heat of the solution is 4.184 J/(g°C) as it is mostly water, therefore, the heat released by the reaction is:
3) Finally, since the enthalpy of reaction is calculated by dividing the heat released by the reaction over the moles of the solute, in this case NH4Cl, we proceed as follows:

Best regards!
Best regards!
Answer:
The number of lines possible for SO2 is 3
Explanation:
The following Procedure should be followed when calculating the number of vibrational modes:-
- Identify if the given molecule is either linear or non-linear
- Calculate the number of atoms present in your molecule
- Place the value of n in the formula and solve.
SO2 is a non-linear molecule because it contains a lone pair which causes the molecule to bent in shape hence, The mathematical formula for calculating the number of non-linear molecule in a infrared region is (3n - 6) here n is the number of atoms in molecule.
hence for Sulphur Dioxide (SO2), n will be 3
<u> Therefore, The number of lines possible for SO2 is (3*3) - 6 = 3</u>
3Si + 2N2 --> Si3N4 (as given)
n(Si) = m/MM = 38.25/28.085 = 1.3619 mol
n(N2) = 14.33/2*14.007 = 0.5115 mol
Therefore, N2 is limiting and Si is in excess
The molar ratio of 2N2:Si3N4 is 2:1
So, 0.0575 mol of silicon nitride is formed (dividing 0.5115 by 2)
m of silicon nitride= n*mm = 0.0575*140.283 = 8.06627... g
= 8.066g (4 significant figures)
(hopefully it is right, but double check in case i did something wrong) :)