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Answer:
Br- Withdraws electrons inductively
Donates electrons by resonance
CH2CH3 - Donates electrons by hyperconjugation
NHCH3- Withdraws electrons inductively
Donates electrons by resonance
OCH3 - Withdraws electrons inductively
Donates electrons by resonance
+N(CH3)3 - Withdraws electrons inductively
Explanation:
A chemical moiety may withdraw or donate electrons by resonance or inductive effect.
Halogens are electronegative elements hence they withdraw electrons by inductive effect. However, they also contain lone pairs so the can donate electrons by resonance.
Alkyl groups donate electrons by hyperconjugation involving hydrogen atoms.
-NHCH3 and contain species that have lone pair of electrons which can be donated by resonance. Also, the nitrogen and oxygen atoms are very electron withdrawing making the carbon atom to have a -I inductive effect.
+N(CH3)3 have no lone pair and is strongly electron withdrawing by inductive effects.
Answer:
The mixture is not in equilibrium, the reaction will shift to the left.
Explanation:
<em>Based on the equilibrium:</em>
<em>Fe³⁺+ HSCN ⇄ FeSCN²⁺ + H⁺</em>
<em>kc = 30 = [FeSCN²⁺] [H⁺] / [Fe³⁺] [HSCN]</em>
Where [] are concentrations at equilibrium. The reaction is in equilibrium when the ratio of concentrations = kc
Q is the same expression than kc but with [] that are not in equilibrium
Replacing:
Q = [10.0M] [1.0M] / [0.1M] [0.1M]
Q = 1000
As Q > kc, the reaction will shift to the left in order to produce Fe³⁺ and HSCN untill Q = Kc
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Answer:
Sp3 hybridization
Explanation:
The NH3 molecule, which consists of one lone pairs and three bond pair of electron on its valance shell due to lone pair bond pair repulsion makes bond angle of 107.5°resulting distorted tetrahedral geometry.
Hybridization =no. of bond pair +lone pair=3+1=4=sp3 hybridization
