Answer:
Explanation:
<u>1) Rate law, at a given temperature:</u>
- Since all the data are obtained at the same temperature, the equilibrium constant is the same.
- Since only reactants A and B participate in the reaction, you assume that the form of the rate law is:
r = K [A]ᵃ [B]ᵇ
<u>2) Use the data from the table</u>
- Since the first and second set of data have the same concentration of the reactant A, you can use them to find the exponent b:
r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s
r₂ = (1.50)ᵃ (2.50)ᵇ = 2.50 × 10⁻¹ M/s
Divide r₂ by r₁: [ 2.50 / 1.50] ᵇ = 1 ⇒ b = 0
- Use the first and second set of data to find the exponent a:
r₁ = (1.50)ᵃ (1.50)ᵇ = 2.50 × 10⁻¹ M/s
r₃ = (3.00)ᵃ (1.50)ᵇ = 5.00 × 10⁻¹ M/s
Divide r₃ by r₂: [3.00 / 1.50]ᵃ = [5.00 / 2.50]
2ᵃ = 2 ⇒ a = 1
<u>3) Write the rate law</u>
This means, that the rate is independent of reactant B and is of first order respect reactant A.
<u>4) Use any set of data to find K</u>
With the first set of data
- r = K (1.50 M) = 2.50 × 10⁻¹ M/s ⇒ K = 0.250 M/s / 1.50 M = 0.167 s⁻¹
Result: the rate constant is K = 0.167 s⁻¹
Answer:This would be heterozygous, so both dominant and recessive alleles are written.
Explanation:Heterozygous means that the dominant and recessive alleles are written genotypically.
Answer:
The percent by mass of copper in the mixture was 32%
Explanation:
The ammount of HNO₃ used is:
mol HNO₃ = volume * concentration
mol HNO₃ = 0.015 l * 15.8 mol/l
mol HNO₃ = 0.237 mol
According to the reaction, 4 mol HNO₃ will react with 1 mol Cu and produce 1 mol Cu²⁺. Since we have 0.237 mol HNO₃, the amount of Cu that could react would be (0.237 mol HNO₃ * 1 mol Cu / 4 mol HNO₃) 0.06 mol. This reaction would produce 0.060 mol Cu²⁺, however, only 0.010 mol Cu²⁺ were obtained, indicating that only 0.010 mol Cu were present in the mixture. This means that the acid was in excess, so we can assume that all copper present in the mixture has reacted.
Since 0.010 mol of Cu²⁺ were produced, the amount of Cu was 0.01 mol.
1 mol of Cu has a mass of 63.5 g, then 0.01 mol has a mass of:
0.01 mol Cu * 63.5 g / 1 mol = 0.635 g.
Since this amount was present in 2.00 g mixture, the amount of copper in 100 g of the mixture will be:
100 g(mixture) * 0.635 g Cu / 2 g(mixture) = 32 g
Then, the percent by mass of Cu (which is the mass of Cu in 100 g mixture) is 32%
