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allsm [11]
3 years ago
15

A student is studying the boiling points of six different liquids and finds results with consistently higher boiling points than

what research would suggest. Which option describes a likely cause?
Chemistry
1 answer:
almond37 [142]3 years ago
4 0

Answer:

Large molecules tend to have greater boiling points because the London dispersion forces are stronger within.

Explanation:

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A gas sample in a closed, expandable container of initial volume 5.00 l was allowed to warm from 25 °c to 35 °
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Charles law states that volume of gas is directly proportional to temperature of gas at constant pressure and fixed amount of gas.
V / T = k
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Which of the following non-hydrogen atom transitions does the photon have at its long wavelength?
suter [353]

Answer:

The move from Level n=3 to Level n=2 has the long wavelength.

Explanation:

First, due to the selection rules, only transitions between adjacent levels are allowed, thus, only a transition between Level n=3 to Level n=2 or Level n=5 to Level n=4 are allowed. The two first options are wrong.

Second, analyzing the transition between Level n=3 to Level n=2 and the transition between Level n=5 to Level n=4 it is necessary to think in terms of the equation of the difference of energy for these type of transitions:

ΔE = \frac{h^{2}}{8.m.L}(n_{LUMO}^{2} -n_{HOMO}^{2} ) (1)

The difference in energy (ΔE) is directly proportional to the quadratic difference between the 'n' levels of transition. Therefore, If the transition occurs between smaller 'n' levels the difference of energy will be smaller too.

Also, the energy (ΔE) is inversely proportional to the wavelength (λ) so a smaller energy means a larger wavelength.

ΔE = c / λ (2)

Hence, the move from Level n=3 to Level n=2 has a long wavelength.

In order to calculate this wavelength is necessary to replace the data on equation (1) and (2).

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