Alcohol is a pure substance
Answer:
See explanation
Explanation:
The reaction that we are considering here is quite a knotty reaction. It is difficult to decide if the mechanism is actually E1 or E2 since both are equally probable based on the mass of scientific evidence regarding this reaction. However, we can easily assume that the methylenecyclohexane was formed by an E1 mechanism.
Looking at the products, one could convincingly assert that the reaction leading to the formation of the two main products proceeds via an E1 mechanism with the formation of a carbocation intermediate as has been shown in mechanism attached to this answer. Possible rearrangement of the carbocation yields the 3-methylcyclohexene product.
<u>Answer:</u> The concentration of
required will be 0.285 M.
<u>Explanation:</u>
To calculate the molarity of
, we use the equation:

Moles of
= 0.016 moles
Volume of solution = 1 L
Putting values in above equation, we get:

For the given chemical equations:

![Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9](https://tex.z-dn.net/?f=Ni%5E%7B2%2B%7D%28aq.%29%2B6NH_3%28aq.%29%5Crightleftharpoons%20%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%2BC_2O_4%5E%7B2-%7D%28aq.%29%3BK_f%3D1.2%5Ctimes%2010%5E9)
Net equation: ![NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?](https://tex.z-dn.net/?f=NiC_2O_4%28s%29%2B6NH_3%28aq.%29%5Crightleftharpoons%20%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%2BC_2O_4%5E%7B2-%7D%28aq.%29%3BK%3D%3F)
To calculate the equilibrium constant, K for above equation, we get:

The expression for equilibrium constant of above equation is:
![K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}](https://tex.z-dn.net/?f=K%3D%5Cfrac%7B%5BC_2O_4%5E%7B2-%7D%5D%5B%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%5D%7D%7B%5BNiC_2O_4%5D%5BNH_3%5D%5E6%7D)
As,
is a solid, so its activity is taken as 1 and so for 
We are given:
![[[Ni(NH_3)_6]^{2+}]=0.016M](https://tex.z-dn.net/?f=%5B%5BNi%28NH_3%29_6%5D%5E%7B2%2B%7D%5D%3D0.016M)
Putting values in above equations, we get:
![0.48=\frac{0.016}{[NH_3]^6}}](https://tex.z-dn.net/?f=0.48%3D%5Cfrac%7B0.016%7D%7B%5BNH_3%5D%5E6%7D%7D)
![[NH_3]=0.285M](https://tex.z-dn.net/?f=%5BNH_3%5D%3D0.285M)
Hence, the concentration of
required will be 0.285 M.
32 DEGREES F
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