<u>Answer:</u>
<u>For 1:</u> The amount of potassium iodate that were titrated is
moles
<u>For 2:</u> The amount of sodium thiosulfate required is
moles
<u>Explanation:</u>
To calculate the number of moles for given molarity, we use the equation:
![\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in L)}}](https://tex.z-dn.net/?f=%5Ctext%7BMolarity%20of%20the%20solution%7D%3D%5Cfrac%7B%5Ctext%7BMoles%20of%20solute%7D%5Ctimes%201000%7D%7B%5Ctext%7BVolume%20of%20solution%20%28in%20L%29%7D%7D)
Molarity of
solution = 0.0100 M
Volume of solution = 25 mL
Putting values in above equation, we get:
![0.0100M=\frac{\text{Moles of }KIO_3\times 1000}{25}\\\\\text{Moles of }KIO_3=\frac{0.0100\times 25}{1000}=0.00025mol](https://tex.z-dn.net/?f=0.0100M%3D%5Cfrac%7B%5Ctext%7BMoles%20of%20%7DKIO_3%5Ctimes%201000%7D%7B25%7D%5C%5C%5C%5C%5Ctext%7BMoles%20of%20%7DKIO_3%3D%5Cfrac%7B0.0100%5Ctimes%2025%7D%7B1000%7D%3D0.00025mol)
Hence, the amount of potassium iodate that were titrated is
moles
The chemical equation for the reaction of potassium iodate and sodium thiosulfate follows:
![2KIO_3+Na_2S_2O_3\rightarrow K_2S_2O_3+2NaIO_3](https://tex.z-dn.net/?f=2KIO_3%2BNa_2S_2O_3%5Crightarrow%20K_2S_2O_3%2B2NaIO_3)
By Stoichiometry of the reaction:
2 moles of potassium iodate reacts with 1 mole of sodium thiosulfate
So, 0.00025 moles of potassium iodate will react with =
of sodium thiosulfate
Hence, the amount of sodium thiosulfate required is
moles