Hi there I believe it’s 18 please let me know if I’m wrong :)
<u>Answer:</u>
<u>For A:</u> The
for the given reaction is 
<u>For B:</u> The
for the given reaction is 1642.
<u>Explanation:</u>
The given chemical reaction follows:

The expression of
for the above reaction follows:

We are given:

Putting values in above equation, we get:

Hence, the
for the given reaction is 
Relation of
with
is given by the formula:

where,
= equilibrium constant in terms of partial pressure = 
= equilibrium constant in terms of concentration = ?
R = Gas constant = 
T = temperature = 500 K
= change in number of moles of gas particles = 
Putting values in above equation, we get:

Hence, the
for the given reaction is 1642.
Gasoline contains C and H atoms. During combustion, the carbon (C) from the fuel combines with oxygen (O2) from the air to produce carbon dioxide (CO2).
2 C8H18 + 25 O2 → 16 CO2 + 18 H2O.
Combustion reactions release large amounts of heat. They have negative enthalpy. A negative enthalpy represents an exothermic reaction, releasing heat. This reaction is spontaneous and exothermic, since we can obtain energy from the reaction; the ΔG (free energy) is negative (So 1 is true).
ΔG < 0, so the free energy of the system decreases with the reaction. Remember that when there is a negative ΔG the reaction goes from higher free energy to lower free energy, like in this case.
567000 would be in grams, hope this helps :)