Answer:
a. 750Hz, b. 4.0ppm, c. 600Hz
Explanation:
The Downfield Shift (Hz) is given by the formula
Downfield Shift (Hz) = Chemical Shift (ppm) x Spectrometer Frequency (Hz)
Using the above formula we can solve all three parts easily
a. fspec = 300 MHz, Chem. Shift = 2.5ppm, 1MHz = 10⁶ Hz, 1ppm (parts per million) = 10⁻⁶
Downfield Shift (Hz) = 2.5ppm x 300MHz x (1Hz/10⁶MHz) x (10⁻⁶/1ppm)
Downfield Shift = 750 Hz
The signal is at 750Hz Downfield from TMS
b. Downfield Shift = 1200 Hz, Chemical Shift = ?
Chemical Shift = Downfield shift/Spectrometer Frequency
Chemical Shift = (1200Hz/300MHz) x (1ppm/10⁻⁶) = 4.0 ppm
The signal comes at 4.0 ppm
c. Separation of 2ppm, Downfield Shift = ?
Downfield Shift (Hz) = 2(ppm) x 300 (MHz) x (1Hz/10⁶MHz) x (10⁻⁶/1ppm) = 600 Hz
The two peaks are separated by 600Hz
High conductivity of metals is caused by electrons that are free to move through the lattice.
hope this helps!
Answer:
The law is observed in the given equation.
Explanation:
CaCO₃ + 2HCI → CaCI₂ +H₂O + CO₂
In order to find out if the law of conservative mass is followed, we need to <u>count how many atoms of each element are there in both sides of the equation</u>:
- Ca ⇒ 1 on the left, 1 on the right.
- C ⇒ 1 on the left, 1 on the right.
- O ⇒ 3 on the left, 3 on the right.
- H ⇒ 2 on the left, 2 on the right.
- Cl ⇒ 2 on the left, 2 on the right.
As the numbers for all elements involved are the same, the law is observed in the given equation.
From the periodic table:
molecular mass of carbon = 12 grams
molecular mass of fluorine = 18.99 grams
molecular mass of chlorine = 35.5 grams
Therefore:
one mole of CF2Cl2 = 12 + 2(18.99) + 2(35.5) = 120.98 grams
Therefore, we can use cross multiplication to find the number of moles in 79.34 grams as follows:
mass = (79.34 x 1) / 120.98 = 0.6558 moles
Now, one mole contains 6.022 x 10^23 molecules, therefore:
number of molecules in 0.65548 moles = 0.6558 x 6.022 x 10^23
= 3.949 x 10^23 molecules
