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deff fn [24]
3 years ago
14

What is the initial temperature (°C) of a system that has the pressure decreased by 10 times while the volume increased by 5 tim

es with a final temperature of 150 K?
Chemistry
1 answer:
Ede4ka [16]3 years ago
8 0

Answer:

300K

Explanation:

Given pressure of the system decreased by 10 times which means P_{2} =\frac{P_{1} }{10}

Given the volume of the system increased by 5 times which means V_{2} =5\times V_{1}

Given final temperature T_{2}=150K

Let the initial temperature be T_{1}

We know that PV=nRT

As n and R are constant \frac{PV}{T}=constant

\frac{P_{1}V_{1} }{T_{1}} =\frac{P_{2}V_{2}}{T_{2}}

T_{1} =\frac{P_1V_1}{P_2V_2} T_{2}

T_{1} =2\times T_{2}

T1=300K

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What is the predicted change in the boiling point of water when 1.50 g of
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⠀

\textsf {While} \:  \sf  {\Delta T_b}  \: \textsf{expression is used} \\  \textsf {for elevation of boiling point}

⠀

⠀

<u>The</u><u> </u><u>elevation</u><u> </u><u>in</u><u> </u><u>boiling</u><u> </u><u>point</u><u> </u><u>is</u><u> </u><u>a</u><u> </u><u>phenomenon</u><u> </u><u>in</u><u> </u><u>which</u><u> </u><u>there</u><u> </u><u>is</u><u> </u><u>increase</u><u> </u><u>in</u><u> </u><u>boiling</u><u> </u><u>point</u><u> </u><u>in</u><u> </u><u>solution</u><u>,</u><u> </u><u>when</u><u> </u><u>the</u><u> </u><u>particular</u><u> </u><u>type</u><u> </u><u>of</u><u> </u><u>solute</u><u> </u><u>is</u><u> </u><u>added</u><u> </u><u>to</u><u> </u><u>pure</u><u> </u><u>solvent</u><u>.</u>

⠀

⠀

\sf  \large \underline{The \:  formula \: to \:  be  \: used \:  in \:  this \:  question \:  is}  \\   \boxed{T_b = i \times  K_b \times  m}

⠀

⠀

Where 'i' is van't hoff factor which represents the ratio of observed osmotic pressure and the value to be expected.

and 'i' is 3 (as given in the question)

⠀

'Kb' is molal boiling point constant. And it's value is 0.51°C/mol(given in question)

⠀

'm' represent the molality of solution. Molatity is no. of moles of solution present in 1kg of solution.

⠀

⠀

<u>To</u><u> </u><u>find</u><u> </u><u>molality</u><u>,</u><u> </u><u>we</u><u> </u><u>have</u><u> </u><u>to</u><u> </u><u>divide</u><u> </u><u>no</u><u>.</u><u> </u><u>of</u><u> </u><u>moles</u><u> </u><u>of</u><u> </u><u>solute</u><u> </u><u>by</u><u> </u><u>weight</u><u> </u><u>of</u><u> </u><u>solution</u>

⠀

While first we need to no. of moles

\sf \implies no. \: of \: moles =  \frac{weight \: of \: solute}{molar \: mass \: of \: solute}  \\  \\ \implies \sf no. \: of \: moles =  \frac{1.5}{208.23}  \\  \\  \sf \implies  no. \: of \: moles = 0.0072

⠀

⠀

<u>Now</u><u>,</u><u> </u><u>we</u><u> </u><u>will</u><u> </u><u>find</u><u> </u><u>molality</u>

⠀

\sf  \hookrightarrow molality =  \frac{no.\: of \: moles}{weight \: of \: solution}  \\  \\  \sf  \hookrightarrow molality =  \frac{0.072}{1.5}  \\  \\  \sf  \hookrightarrow molality = 0.048 \: mol {kg}^{ - 1}

⠀

⠀

\textsf{ \large{ \underline{Now substituting the required values}}}

⠀

\sf \longmapsto \Delta T_b = 3  \times 0.51  \times 0.0048 \\  \\ \\     \boxed{ \tt{ \longmapsto \Delta T_b =0.00735{ \degree}C}}

⠀

⠀

⠀

<u>Henceforth</u><u>,</u><u> </u><u>the</u><u> </u><u>change</u><u> </u><u>in</u><u> </u><u>boiling</u><u> </u><u>point</u><u> </u><u>is</u><u> </u><u>0</u><u>.</u><u>0</u><u>0</u><u>7</u><u>3</u><u>5</u><u>°</u><u>C</u><u>.</u>

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