Consider the substitution reaction that rakes place when (R)-3-bromo 3-methylhexane is treated with methanol. Which of the follo
wing would be true? The reaction would take place only with inversion of configuration at the center. The reaction would take place only with retention of configuration at the center. The reaction would take place with racemization. No reaction would take place. The alkyl halide does not possess a center.
1 answer:
Answer:
The reaction would take place with racemization.
Explanation:
The compound (R)-3-bromo 3-methylhexane contains has the leaving group attached to a tertiary carbon atom. When the leaving group is attached to a tertiary carbon atom, the compound undergoes nucleophilic substitution via SN1 mechanism. This mechanism involves the formation of a planar carbocation intermediate. The nucleophile may attack this intermediate from either faces, leading to racemization of the product.
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Balance the equation first:
2 KClO3 (s) ---> 2 KCl (s) + 3 O2 (g)
Moles of KClO3 = 110 / 122.5 = 0.89
Following the balanced chemical equation:
We can say moles of O2 produce =
x moles of KClO3
So, O2 = (3 / 2) x 0.89
= 1.34 moles
So, Volume at STP = nRT / P
T = <span>273.15 K
P = 1 atm
So, V = (1.34 x 0.0821 x 273.15) / 1 = 30.2 L</span>
2 KClO3 (s) ---> 2 KCl (s) + 3 O2 (g)
Moles of KClO3 = 110 / 122.5 = 0.89
Following the balanced chemical equation:
We can say moles of O2 produce =
So, O2 = (3 / 2) x 0.89
= 1.34 moles
So, Volume at STP = nRT / P
T = <span>273.15 K
P = 1 atm
So, V = (1.34 x 0.0821 x 273.15) / 1 = 30.2 L</span>
<u>Answer:</u> The for the reaction is -1835 kJ.
<u>Explanation:</u>
Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.
According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.
The given chemical reaction follows:
The intermediate balanced chemical reaction are:
(1)
( × 4)
(2)
The expression for enthalpy of the reaction follows:
Putting values in above equation, we get:
Hence, the for the reaction is -1835 kJ.
Answer: The correct answer is option B.
Explanation: There are 7 elements in group VIII-A. They are Helium (He), Neon(Ne), Argon(Ar), Krypton (Kr), Xenon (Xe), Radon (Rn) and Ununoctium (Uuo). They are considered as a part of group 18.
Metals are shown in purple color in the periodic table. Metalloids as blue color and Non-metals are shown in green color.
Group VIII-A elements have fully filled orbitals and hence are most stable amongst all the elements in the periodic table. They are considered as least reactive elements and as they are categorized as non-metals. So, they are the least reactive non-metals.
Therefore, the correct option is B.
