Consider the substitution reaction that rakes place when (R)-3-bromo 3-methylhexane is treated with methanol. Which of the follo
wing would be true? The reaction would take place only with inversion of configuration at the center. The reaction would take place only with retention of configuration at the center. The reaction would take place with racemization. No reaction would take place. The alkyl halide does not possess a center.
1 answer:
Answer:
The reaction would take place with racemization.
Explanation:
The compound (R)-3-bromo 3-methylhexane contains has the leaving group attached to a tertiary carbon atom. When the leaving group is attached to a tertiary carbon atom, the compound undergoes nucleophilic substitution via SN1 mechanism. This mechanism involves the formation of a planar carbocation intermediate. The nucleophile may attack this intermediate from either faces, leading to racemization of the product.
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Considering the ideal gas law, a sample weighing 9.49 g occupies 68.67 L at 353 K and 2.00 atm.
Ideal gases are a simplification of real gases that is done to study them more easily. It is considered to be formed by point particles, do not interact with each other and move randomly. It is also considered that the molecules of an ideal gas, in themselves, do not occupy any volume.
An ideal gas is characterized by three state variables: absolute pressure (P), volume (V), and absolute temperature (T). The relationship between them constitutes the ideal gas law, an equation that relates the three variables if the amount of substance, number of moles n, remains constant and where R is the molar constant of the gases:
P× V = n× R× T
In this case, you know:
- P= 2 atm
- V= ?
- n=
being 2g/mole the molar mass of H2, that is, the amount of mass that a substance contains in one mole.
- R= 0.082
- T= 353 K
Replacing:
2 atm× V = 4.745 moles× 0.082× 353 K
Solving:
V = (4.745 moles× 0.082× 353 K)÷ 2 atm
<u><em>V= 68.67 L</em></u>
Finally, a sample weighing 9.49 g occupies 68.67 L at 353 K and 2.00 atm.
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