Liquidification of gases

Chemistry

1 answer:

larisa86 [58]3 years ago

6 0

Answer:

the process by which substances in their gaseous state are converted to the liquid state.

Explanation:

When pressure on a gas is increased, its molecules closer together, and its temperature is reduced, which removes enough energy to make it change from the gaseous to the liquid state.

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One kilogram of water at 100 0C is cooled reversibly to 15 0C. Compute the change in entropy. Specific heat of water is 4190 J/K

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Answer:

The change in entropy is -1083.112 joules per kilogram-Kelvin.

Explanation:

If the water is cooled reversibly with no phase changes, then there is no entropy generation during the entire process. By the Second Law of Thermodynamics, we represent the change of entropy ( $s_{2} - s_{1}$ ), in joules per gram-Kelvin, by the following model:

$s_{2} - s_{1} = \int\limits^{T_{2}}_{T_{1}} {\frac{dQ}{T} }$

$s_{2} - s_{1} = m\cdot c_{w} \cdot \int\limits^{T_{2}}_{T_{1}} {\frac{dT}{T} }$

$s_{2} - s_{1} = m\cdot c_{w} \cdot \ln \frac{T_{2}}{T_{1}}$ (1)

Where:

$m$ - Mass, in kilograms.

$c_{w}$ - Specific heat of water, in joules per kilogram-Kelvin.

$T_{1}$ , $T_{2}$ - Initial and final temperatures of water, in Kelvin.

If we know that $m = 1\,kg$ , $c_{w} = 4190\,\frac{J}{kg\cdot K}$ , $T_{1} = 373.15\,K$ and $T_{2} = 288.15\,K$ , then the change in entropy for the entire process is: