Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.
Refer to to this chart
Credits to <span>https://image.slidesharecdn.com/nybf09-unit2slides26-57-100125181507-phpapp01/95/nyb-f09-unit-2-slid...
As temperature decreases, rate decreases.
As temp increases, k also increases. </span>
Answer:
Float
Explanation:
If the weight of liquid displaced and the weight of an object are the same, the object will float in the liquid.
From Archimedes principle, when an object is immersed in fluid, a force called upthrust supports it and it equal to the weight of the liquid displaced.
When in a liquid, the weight of the liquid displaced is the same as that of the of the object, it will float and not sink.
6 CO₂ + 6 H₂O (chlorophyll + sunlight) ⇒ C₆H₁₂O₆ + 6 O₂
the reaction takes place in presence of sunlight and chlorophyll ..
CO₂ is oxidized and forms Glucose . And oxygen is evolved in this process.
The correct choice in the options above is the aerosols. It is because the aerosols are the ones that are combined with gaseous substances and water in order for it to be formed. Without the gaseous substance being joined with the water then the aerosols won't be produced.