Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
V1M1 = V2M2
<span>V1 × 2.5 = 1 × 0.75,
so V1 = 0.75/2.5
= 0.3 </span>
Answer: a
Explanation:
Industry uses only about 18% while the others use around 70-90% of water.
YW!!! please mark branlest!!!! =^.^=
Answer:
0.007 mol
Explanation:
We can solve this problem using the ideal gas law:
PV = nRT
where P is the total pressure, V is the volume, R the gas constant, T is the temperature and n is the number of moles we are seeking.
Keep in mind that when we collect a gas over water we have to correct for the vapor pressure of water at the temperature in the experiment.
Ptotal = PH₂O + PO₂ ⇒ PO₂ = Ptotal - PH₂O
Since R constant has unit of Latm/Kmol we have to convert to the proper unit the volume and temperature.
P H₂O = 23.8 mmHg x 1 atm/760 mmHg = 0.031 atm
V = 1750 mL x 1 L/ 1000 mL = 0.175 L
T = (25 + 273) K = 298 K
PO₂ = 1 atm - 0.031 atm = 0.969 atm
n = PV/RT = 0.969 atm x 0.1750 L / (0.08205 Latm/Kmol x 298 K)
n = 0.007 mol
the density increases down the group.
