Answer:To convert the model of one constitutional isomer to another constitutional isomer one needs to exchange 2 atoms/groups on different atoms.
To convert the model of one stereoisomer to another stereoisomer one needs to exchange 2 atoms/groups bonded to the same carbon.
To convert the model of one conformational isomer to another conformational isomer one only needs to rotate about single bond(s).
Explanation:
Constitutional isomers differ from each other in position of substituents. Hence if we interchange atoms or groups on two different atoms, we get constitutional isomers.
Stereo isomers posses different orientations in space. If two atoms or groups on the same carbon atoms interchange their spatial orientation, we have a different stereoisomer other than the original structure.
Conformers arise by free rotation across single bonds. Different conformers can be created by rotating single bonds.
Answer:
A. Methanol
B. 2-chloropropan-1-ol
C. 2,2-dichloroethanol
D. 2,2-difluoropropan-1-ol
Explanation:
Primary alcohols are stronger acids than secondary alcohols which are stronger than tertiary alcohols.
This trend is so because of the stability of the alkoxide ion formed(stabilising the base, increases the acidity). A more stabilised alkoxide ion is a weaker conjugate base (dissociation of an acid in water).
By electronic factors, When there are alkyl groups donating electrons, the density of electrons on th O- will increase a d thereby make it less stable.
By stearic factors, More alkyl group bonded to the -OH would mean the bulkier the alkoxide ion which would be harder to stabilise.
Down the group of the periodic table, basicity (metallic character) decreases as we go from F– to Cl– to Br– to I– because that negative charge is being spread out over a larger volume that is electronegativity decreases down the group.
Electronegative atoms give rise to inductive effect and a decrease in indutive effects leads to a decrease in acidity. Therefore an Increasing distance from the -OH group lsads to a decrease in acidity.
From above,
A. Methanol
B. 2-chloropropan-1-ol
C. 2,2-dichloroethanol
D. 2,2-difluoropropan-1-ol
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