Answer:
626.7nm
Explanation:
The energy of a photon is defined as:
E = hc / λ
<em>Where E is the energy of the photon, h is Planck constant (6.626x10⁻³⁴Js), c is speed of light (3x10⁸m/s) and </em>λ is the wavelength of light
The energy of 1 photon is:
(191000 J / mol) ₓ (1 mole / 6.022x10²³) = 3.1717x10⁻¹⁹ J
Replacing:
3.1717x10⁻¹⁹ J = <em>6.626x10⁻³⁴Jsₓ3x10⁸m/s / </em>λ
λ = 6.267x10⁻⁷m
as 1nm = 1x10⁻⁹m:
6.267x10⁻⁷m ₓ (1nm / 1x10⁻⁹m) =
<h3>626.7nm</h3>
Answer:
a) Xbenzene = 0.283
b) Xtoluene = 0.717
Explanation:
At T = 20°C:
⇒ vapor pressure of benzene (P*b) = 75 torr
⇒ vapor pressure toluene (P*t) = 22 torr
Raoult's law:
∴ Pi: partial pressure of i
∴ Xi: mole fraction
∴ P*i: vapor pressure at T
a) solution: benzene (b) + toluene (t)
∴ Psln = 37 torr; at T=20°C
⇒ Psln = Pb + Pt
∴ Pb = (Xb)*(P*b)
∴ Pt = (Xt)*(P*t)
∴ Xb + Xt = 1
⇒ Psln = 37 torr = (Xb)(75 torr) + (1 - Xb)(22 torr)
⇒ 37 torr - 22 torr = (75 torr)Xb - (22 torr)Xb
⇒ 15 torr = 53 torrXb
⇒ Xb = 15 torr / 53 torr
⇒ Xb = 0.283
b) Xb + Xt = 1
⇒ Xt = 1 - Xb
⇒ Xt = 1 - 0.283
⇒ Xt = 0.717
Answer:
1.64x10⁻¹⁸ J
Explanation:
By the Bohr model, the electrons surround the nucleus of the atom in shells or levels of energy. Each one has it's energy, and the electron doesn't fall to the nucleus because it can reach another level of energy, and then return to its level.
When the electrons go to another level, it absorbs energy, and then, when return, this energy is released, as a photon (generally as luminous energy). The value of the energy can be calculated by:
E = hc/λ
Where h is the Planck constant (6.626x10⁻³⁴ J.s), c is the light speed (3.00x10⁸ m/s), and λ is the wavelength of the photon.
The wavelength can be calculated by:
1/λ = R*(1/nf² - 1/ni²)
Where R is the Rydberg constant (1.097x10⁷ m⁻¹), nf is the final orbit, and ni the initial orbit. So:
1/λ = 1.097x10⁷ *(1/1² - 1/2²)
1/λ = 8.227x10⁶
λ = 1.215x10⁻⁷ m
So, the energy is:
E = (6.626x10⁻³⁴ * 3.00x10⁸)/(1.215x10⁻⁷)
E = 1.64x10⁻¹⁸ J
