
As long as the equation in question can be expressed as the sum of the three equations with known enthalpy change, its
can be determined with the Hess's Law. The key is to find the appropriate coefficient for each of the given equations.
Let the three equations with
given be denoted as (1), (2), (3), and the last equation (4). Let
,
, and
be letters such that
. This relationship shall hold for all chemicals involved.
There are three unknowns; it would thus take at least three equations to find their values. Species present on both sides of the equation would cancel out. Thus, let coefficients on the reactant side be positive and those on the product side be negative, such that duplicates would cancel out arithmetically. For instance,
shall resemble the number of
left on the product side when the second equation is directly added to the third. Similarly
Thus
and

Verify this conclusion against a fourth species involved-
for instance. Nitrogen isn't present in the net equation. The sum of its coefficient shall, therefore, be zero.

Apply the Hess's Law based on the coefficients to find the enthalpy change of the last equation.

Question #1
Potasium hydroxide (known)
volume used is 25 ml
Molarity (concentration) = 0.150 M
Moles of KOH used
0.150 × 25/1000 = 0.00375 moles
Sulfuric acid (H2SO4)
volume used = 15.0 ml
unknown concentration
The equation for the reaction is
2KOH (aq)+ H2SO4(aq) = K2SO4(aq) + 2H2O(l)
Thus, the Mole ratio of KOH to H2SO4 is 2:1
Therefore, moles of H2SO4 used will be;
0.00375 × 1/2 = 0.001875 moles
Acid (sulfuric acid) concentration
0.001875 moles × 1000/15
= 0.125 M
Question #2
Hydrogen bromide (acid)
Volume used = 30 ml
Concentration is 0.250 M
Moles of HBr used;
0.25 × 30/1000
= 0.0075 moles
Sodium Hydroxide (base)
Volume used 20 ml
Concentration (unknown)
The equation for the reaction is
NaOH + HBr = NaBr + H2O
The mole ratio of NaOH : HBr is 1 : 1
Therefore, moles of NaOH used;
= 0.0075 moles
NaOH concentration will be
= 0.0075 moles × 1000/20
= 0.375 M
expect what to have?!?!?!?
Answer:
propane -1 2 3 - trioic acid
it's the first one. the one with ox in it