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lbvjy [14]
3 years ago
14

g In the elimination reaction of t-butanol and t-butyl bromide. A. They have a common intermediate and require a strong base B.

Both reactions share a common intermediate and involve a similar leaving group C. One reaction goes through an E1 mechanism and the other an E2 mechanism D. Both reactions share a common intermediate and differ only in the leaving group
Chemistry
1 answer:
11111nata11111 [884]3 years ago
6 0

Answer:

Both reactions share a common intermediate and differ only in the leaving group

Explanation:

The elimination reaction of tertiary alkyl halides usually occur by E1 mechanism. In E1 mechanism, the substrate undergoes ionization leading to the loss of a leaving group and formation of a carbocation.

Loss of a proton from the carbocation completes the reaction mechanism yielding the desired alkene.

In the cases of t-butanol and t-butyl bromide, the mechanism is the same. The both reactions proceed by E1 mechanism. The leaving groups in each case are water and chloride ion respectively.

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What is the percentage of s-character in an sp hybrid? O 25% 50% o 75% O 66%
marishachu [46]

Answer: 50%

Explanation:

The number of electron pairs are 2 for hybridization to be sp and the electronic geometry of the molecule will be linear.

1. percentage of s character in sp hybrid orbital =\frac{\text {number of s orbitals}}{\text {total number of orbitals}}=\frac{1}{2}\times 100=50\%

2. percentage of s character in sp^2 hybrid orbital =\frac{\text {number of s orbitals}}{\text {total number of orbitals}}=\frac{1}{3}\times 100=33.3\%

3. percentage of s character in sp^3 hybrid orbital =\frac{\text {number of s orbitals}}{\text {total number of orbitals}}=\frac{1}{4}\times 100=25\%

Thus percentage of s-character in an sp hybrid is 50%.

8 0
3 years ago
Which of the compounds above are strong enough acids to react almost completely with a hydroxide ion (pka of h2o = 15.74) or wit
luda_lava [24]

The compounds can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Further explanation </em></h3>

In an acid-base reaction, it can be determined whether or not a reaction occurs by knowing the value of pKa or Ka from acid and conjugate acid (acid from the reaction)

Acids and bases according to Bronsted-Lowry

Acid = donor (donor) proton (H + ion)

Base = proton (receiver) acceptor (H + ion)

If the acid gives (H +), then the remaining acid is a conjugate base because it accepts protons. Conversely, if a base receives (H +), then the base formed can release protons and is called the conjugate acid from the original base.

From this, it can be seen whether the acid in the product can give its proton to a base (or acid which has a lower Ka value) so that the reaction can go to the right to produce the product.

The step that needs to be done is to know the pKa value of the two acids (one on the left side and one on the right side of the arrow), then just determine the value of the equilibrium constant

Can be formulated:

K acid-base reaction = Ka acid on the left : K acid on the right.

or:

pK = acid pKa on the left - pKa acid on the right

K = equilibrium constant for acid-base reactions

pK = -log K;

K~=~10^{-pK}

K value> 1 indicates the reaction can take place, or the position of equilibrium to the right.

There is some data that we need to complete from the problem above, which is the pKa value of some compounds that will react, namely:

pyridinium pKa = 5.25

acetone pKa = 19.3

butan-2-one pKa = 19

Let's look at the K value of each possible reaction:

pka H₂O = 15.74, pka of H₂CO₃ = 6.37)

  • 1. C₅H₆N pyridinium

* with OH⁻

C₅H₆N + OH- ---> C₅H₅N- + H₂O

pK = pKa pyridinium - pKa H₂O

pK = 5.25 - 15.74

pK = -10.49

K~=~10^{4.9}

K values> 1 indicate the reaction can take place

* with HCO3⁻

C₅H₆N + HCO₃⁻-- ---> C₅H₅N⁻ + H₂CO₃

pK = 5.25 - 6.37

pK = -1.12

K`=~10^{1.12]

Reaction can take place

  • 2. Acetone C₃H₆O

* with OH-

C₃H₆O + OH⁻ ---> C₃H₅O- + H₂O

pK = 19.3 - 15.74

pK = 3.56

K~=~10^{ -3.56}

Reaction does not happen

* with HCO₃-

C₃H₆O + HCO₃⁻ ----> C₃H₅O⁻ + H₂CO₃

pK = 19.3 - 6.37

pK = 12.93

K`=~10 ^{-12.93}

Reaction does not happen

  • 3. butan-2-one C₄H₇O

* with OH-

C₄H₇O + OH- ---> C₄H₆O- + H₂O

pK = 19 - 15.74

pK = 3.26

K~=~10^{-3.26}

Reaction does not happen

* with HCO₃⁻

C₄H₇O + HCO₃⁻ ---> C₄H₆O⁻ + H₂CO₃

pK = 19 - 6.37

pK = 12.63

K~=~ 10^{-12.63}

Reaction does not happen

So that can react with OH⁻ and HCO₃⁻ only C₅H₆N pyridinium

<h3><em>Learn more </em></h3>

the lowest ph

brainly.com/question/9875355

the concentrations at equilibrium.

brainly.com/question/8918040

the ph of a solution

brainly.com/question/9560687

Keywords : acid base reaction, the equilibrium constant

5 0
3 years ago
Read 2 more answers
Which salt shows the least solubility change when the temperature is increased from 0 to 100 c?
Hunter-Best [27]
Sodium chloride (NaCl), whose only changes about 5g/100mL water over that entire range 100°C)
4 0
3 years ago
Read 2 more answers
A sample of chlorine gas is at 300K and 1.00 atm. At what temperature and pressure would it behave more like an ideal gas?
Fofino [41]

In lower temperatures, the molecules of real gases tend to slow down enough that the attractive forces between the individual molecules are no longer negligible. In high pressures, the molecules are forced closer together- as opposed to the further distances between molecules at lower pressures. This closer the distance between the gas molecules, the more likely that attractive forces will develop between the molecules. As such, the ideal gas behavior occurs best in high temperatures and low pressures. (Answer to your question: C)  This is because  the attraction between molecules are assumed to be negligible in ideal gases, no interactions and transfer of energy between the molecules occur, and as temperature decreases and pressure increases, the more the gas will act like an real gas.

3 0
4 years ago
Which solution below has the highest concentration of hydroxide ions?a. pH= 3.21b. pH= 7.00c. pH= 7.93d. pH= 12.59e. pH= 9.82
Sloan [31]

Answer:

  • <em>The solution that has the highest concentration of hydroxide ions is </em><u>d. pH = 12.59.</u>

Explanation:

You can solve this question using just some chemical facts:

  1. pH is a measure of acidity or alkalinity: the higher the pH the lower the acidity and the higher the alkalinity.
  2. The higher the concentration of hydroxide ions the lower the acidity or the higher the alkalinity of the solution, this is the higher the pH.

Hence, since you are asked to state the solution with the highest concentration of hydroxide ions, you just pick the highest pH. This is the option d, pH = 12.59.

These mathematical relations are used to find the exact concentrations of hydroxide ions:

  • pH + pOH = 14 ⇒ pOH = 14 - pH

  • pOH = - log [OH⁻] ⇒ [OH^-]=10^{-pOH}

Then, you can follow these calculations:

Solution    pH        pOH                            [OH⁻]

a.               3.21       14 - 3.21 = 10.79        antilogarithm of 10.79 = 1.6 × 10⁻¹¹

b.               7.00      14 - 7.00 = 7.00        antilogarithm of 7.00 = 10⁻⁷

c.                7.93      14 - 7.93 = 6.07        antilogarithm of 6.07 = 8.5 × 10⁻⁷

d.               12.59     14 - 12.59 = 1.41        antilogarithm of 1.41 = 0.039

e.               9.82      14 - 9.82 = 4.18        antilogarithm of 4.18 = 6.6 × 10⁻⁵

From which you see that the highest concentration of hydroxide ions is for pH = 12.59.

5 0
3 years ago
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