Heat of Fusion = 2.05 * 10^5 J / kg watch the units.
Heat to actually melt the copper = 82 10^5 J
Formula
Mass of copper = Heat / Heat of Fusion
Solution
Mass of copper = 82*10^5 J / (2.05 * 10^5 J / kg)
Mass of copper = 40 kg
Notice that the kg is in the denominator of the second fraction. The rules of fractions would tell you the 1/1 / / 1 /kg . You take the right fraction and turn it upside down and multiply. 1 / 1 * kg/1 = 1* kg / 1*1 which is just kg.
Water expands when frozen and physically forces the rock apart. When water falls into rock cracks and freezes, As water expands on freezing it puts pressure on the walls of the rock deepening the crack and breaking it.