Hydrochloride acid +_________ zinc chloride +hydrogen
1 answer:
You might be interested in
Answer:
(A) 0.129 M
(B) 0.237 M
Explanation:
(A) The reaction between potassium hydrogen phthalate and barium hydroxide is:
- 2HA + Ba(OH)₂ → BaA₂ + 2H₂O
Where A⁻ is the respective anion of the monoprotic acid (KC₈H₄O₄⁻).
We <u>convert mass of phthalate to moles</u>, using its molar mass:
- 0.978 g ÷ 156 g/mol = 9.27x10⁻³ mol = 9.27 mmol
Now we <u>convert mmol of HA to mmol of Ba(OH)₂</u>:
- 9.27 mmol HA *
= 6.64 mmol Ba(OH)₂
Finally we calculate the molarity of the Ba(OH)₂ solution:
- 6.64 mmol / 35.8 mL = 0.129 M
(B) The reaction between Ba(OH)₂ and HCl is:
- 2HCl + Ba(OH)₂ → BaCl₂ + 2H₂O
So<u> the moles of HCl that reacted </u>are:
- 17.1 mL * 0.129 M *
= 4.41 mmol HCl
And the <u>molarity of the HCl solution is</u>:
- 4.41 mmol / 18.6 mL = 0.237 M
First we have to find Ka1 and Ka2
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =![\frac{[H^+][HC2O4^-]}{[H2C2O4]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BH%5E%2B%5D%5BHC2O4%5E-%5D%7D%7B%5BH2C2O4%5D%7D%20)
= x² / 0.0356 - x
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6