Question

In general, when the addition of an unsymmetrical electrophilic reagent to an unsymmetrical alkene forms the product predicted by Markovnikov's rule, that occurs because: A) the product is statistically favored. B) steric hindrance favors its formation. C) it is formed via the more/most stable carbocation. D) it is the more/most stable product. E) All of these choices are reasons.

Answer 1

It is formed via the more/most stable carbocation.

What justification exists for Markovnikov's Rule?

A carbocation is created as a result of the protonation of the alkene by the protic acid. The carbocation that has the most alkyl substituents on its carbon holds the positive charge, making it the most stable carbocation. As a result, the addition of the halide to the carbon that has fewer hydrogen substituents makes up the majority of the product.

Markovnikov's rule

According to the Markovnikov rule, a proton is added to the carbon atom with the greatest number of hydrogen atoms connected in addition to processes involving alkenes or alkynes.

Anti-Markovnikov Rule

According to the Anti-Markovnikov Rule, in addition to reactions between alkenes or alkynes, The carbon atom with the fewest hydrogen atoms linked to it receives the proton.

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