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Oksi-84 [34.3K]
3 years ago
8

How many liters of 0.305 M K3PO4 solution are necessary to completely react with 187 mL of 0.0184 M NiCl2 according to the balan

ced chemical reaction?
Chemistry
1 answer:
Mashutka [201]3 years ago
5 0

Answer:

6.55 mL of K₃PO₄ are required

Explanation:

We need to propose the reaction, in order to begin:

2K₃PO₄ (aq) + 3NiCl₂(aq) →  Ni₃(PO₄)₂ (s) ↓ + 6KCl (aq)

Molarity = mol/L (Moles of solute that are contained in 1 L of solution.)

M = mol / volume(L).  Let's find out the moles of chloride:

- We first convert the volume from mL to L → 187 mL . 1L / 1000mL = 0.187L

0.0184 M . 0.187L = 0.00344 moles of NiCl₂

Ratio is 3:2. Let's propose this rule of three:

3 moles of chloride react with 2 moles of phosphate

Then, 0.00344 moles of NiCl₂ will react with (0.00344 . 2) /3 = 0.00229 moles of K₃PO₄

M = mol / volume(L) → Volume(L) = mol/M

Volume(L) = 0.00229 mol / 0.350 M = 6.55×10⁻³L

We convert the volume from L to mL → 6.55×10⁻³L . 1000mL /1L = 6.55 mL

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The percentage of amine is protonated is 63,07%

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The kb is defined as:

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As kb = 4,004x10⁻⁵ and [OH⁻] is 10^{-(14-9,370)}=2,344x10^{-5}:

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As the total amine is a 100%:

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Replacing (1) in (2):

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