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Alenkinab [10]
2 years ago
11

identify the reagents necessary to achieve each of the following transformations o3 dms, pcc, ch2cl, h2so4,h2o,hgso4

Chemistry
1 answer:
hoa [83]2 years ago
3 0

the reagents necessary to convert alcohol to ketoneNa_2Cr_2O_7 , H_2O which involves oxidation of alcohols.

<h3>What is oxidation of alcohols?</h3>
  • Alcohol oxidation is a significant organic chemistry process. Secondary alcohols can be oxidized to produce ketones, while primary alcohols can be oxidized to produce aldehydes and carboxylic acids.
  • In contrast, tertiary alcohols cannot be oxidized without the C-C bonds in the molecule being broken.
  • In order to cause primary alcohols to oxidize into aldehydes
  1. Cr_2O_7 ^-^2 (dichromate)
  2. CrO_3/pyridine (Collins reagent)
  3. Chromium pyridinium compound (PCC)
  4. Dichromate of pyridinium (PDC, Cornforth reagent)
  5. Periodinane by Dess-Martin
  6. Oxalyl chloride with dimethylsulfoxide (DMSO) for Swern
  • oxidation of secondary alcohols to ketones
  1. Cr_2O_7 ^-^2 (dichromate)
  2. CrO_3/pyridine (Collins reagent)
  3. Chromium pyridinium compound (PCC)
  4. Dichromate of pyridinium (PDC, Cornforth reagent)
  5. Periodinane by Dess-Martin
  6. Oxalyl chloride and dimethyl sulfoxide (DMSO) (Swern oxidation)
  7. CrO_3, H_2SO_4/acetone (Jones oxidation)
  8. Acetone with aluminum isopropoxide (Oppenauer oxidation)

To learn more about oxidation of alcohols with the given link

brainly.com/question/7207863

#SPJ4

<u>Question:</u>

Identify the reagents necessary to achieve each of the following transformations

a. O_3 , DMS

b.H_2SO_4 , H_2O , HgSO_4

c.Na_2Cr_2O_7 , H_2O

d.Fe ^ {2+}, NaOH

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2 years ago
The balanced equation for water is 2 H2 + O2 to 2 H2O. If I have 21.2g of a product , and I started with 5.6 g of H2, how many g
ANTONII [103]

Since 21.2 g H2O was produced, the amount of oxygen that reacted can be obtained using stoichiometry. The balanced equation was given:  2H₂ + O₂ → 2H₂O and the molar masses of the relevant species are also listed below. Thus, the following equation is used to determine the amount of oxygen consumed.

Molar mass of H2O = 18 g/mol

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21.2 g H20 x 1 mol H2O/ 18 g H2O x 1 mol O2/ 2 mol H2O x 32 g O2/ 1 mol O2 = 18.8444 g O2

<span>We then determine that 18.84 g of O2 reacted to form 21.2 g H2O based on stoichiometry. It is important to note that we do not need to consider the amount of H2 since we can derive the amount of O2 from the product. Additionally, the amount of H2 is in excess in the reaction.</span>

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