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Alenkinab [10]
2 years ago
11

identify the reagents necessary to achieve each of the following transformations o3 dms, pcc, ch2cl, h2so4,h2o,hgso4

Chemistry
1 answer:
hoa [83]2 years ago
3 0

the reagents necessary to convert alcohol to ketoneNa_2Cr_2O_7 , H_2O which involves oxidation of alcohols.

<h3>What is oxidation of alcohols?</h3>
  • Alcohol oxidation is a significant organic chemistry process. Secondary alcohols can be oxidized to produce ketones, while primary alcohols can be oxidized to produce aldehydes and carboxylic acids.
  • In contrast, tertiary alcohols cannot be oxidized without the C-C bonds in the molecule being broken.
  • In order to cause primary alcohols to oxidize into aldehydes
  1. Cr_2O_7 ^-^2 (dichromate)
  2. CrO_3/pyridine (Collins reagent)
  3. Chromium pyridinium compound (PCC)
  4. Dichromate of pyridinium (PDC, Cornforth reagent)
  5. Periodinane by Dess-Martin
  6. Oxalyl chloride with dimethylsulfoxide (DMSO) for Swern
  • oxidation of secondary alcohols to ketones
  1. Cr_2O_7 ^-^2 (dichromate)
  2. CrO_3/pyridine (Collins reagent)
  3. Chromium pyridinium compound (PCC)
  4. Dichromate of pyridinium (PDC, Cornforth reagent)
  5. Periodinane by Dess-Martin
  6. Oxalyl chloride and dimethyl sulfoxide (DMSO) (Swern oxidation)
  7. CrO_3, H_2SO_4/acetone (Jones oxidation)
  8. Acetone with aluminum isopropoxide (Oppenauer oxidation)

To learn more about oxidation of alcohols with the given link

brainly.com/question/7207863

#SPJ4

<u>Question:</u>

Identify the reagents necessary to achieve each of the following transformations

a. O_3 , DMS

b.H_2SO_4 , H_2O , HgSO_4

c.Na_2Cr_2O_7 , H_2O

d.Fe ^ {2+}, NaOH

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Mass defect for oxygen-16 = 0. 13261 amu, in the kilograms the mass defect equals to 2.20 × 10⁻²⁸ kg.

<h3>What is mass defect?</h3>

Mass defect is the difference between the mass of of an whole atom and the combined mass of its individual particles present in that atom.

We know that, 1 amu = 1.6 × 10⁻²⁷ kg

Given that, mass defect for oxygen-16 = 0.13261 amu

To calculate this defect in terms of kilograms, we have to convert into kg unit as:

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0.13261 amu = 2.20 × 10⁻²⁸ kg

Hence option (2) is correct.

To know more about Mass defect, visit the below link:

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