The equilibrium reaction is
N2O4(g)<----> 2NO2(g)
For reaction
Kp = (pNO2)^2 / pN2O4
Given:
Kp = 0.316
pN2O4 = 3.48 atm
To calculate
pNO2 = ?
0.316 = (pNO2)^2 / 3.48
(pNO2)^2 = 1.0997
pNO2 = 1.049 atm
Answer:
Kc = 0.075
Explanation:
The dissociation (α) is the initial quantity that ionized divided by the total dissolved. So, let's calling x the ionized quantity, and M the initial one:
α = x/M
x = M*α
x = 0.354M
For the stoichiometry of the reaction (2:1:1), the concentration of H₂ and I₂ must be half of the acid. So the equilibrium table must be:
2HI(g) ⇄ H₂(g) + I₂(g)
M 0 0 <em> Initial</em>
-0.354M +0.177M +0.177M <em>Reacts</em>
0.646M 0.177M 0.177M <em>Equilibrium</em>
The equilibrium constant Kc is the multiplication of the products' concentrations (elevated by their coefficients) divided by the multiplication of the reactants' concentrations (elevated by their coefficients):
![Kc = \frac{[H2]*[I2]}{[HI]^2}](https://tex.z-dn.net/?f=Kc%20%3D%20%5Cfrac%7B%5BH2%5D%2A%5BI2%5D%7D%7B%5BHI%5D%5E2%7D)


Kc = 0.075