Question

You know the following about a coordination compound:(1) The partial empirical formula is KM(CrO₄)Cl₂(NH₃)₄.(2) It has A (red) and B (blue) crystal forms.(3) When 1.0 mol of A or B reacts with 1.0 mol of AgNO3,0.50 mol of a red precipitate forms immediately.(4) After the reaction in (3), 1.0 mol of A reacts very slowly with 1.0 mol of silver oxalate (Ag₂C₂O₄) to form 2.0 mol of a white precipitate. (Oxalate can displace other ligands.)(5) After the reaction in (3), 1.0 mol of B does not react further with 1.0 mol of AgNO₃.From this information, determine the following:(c) The stereochemistry of the red and blue forms

Answer 1

Stereochemistry, a subdiscipline of chemistry, involves the study of the relative spatial arrangement of atoms that form the structure of molecules and their manipulation.

What is the use of stereochemistry?

Using stereochemistry, chemists can work out the relationships between different molecules that are made up from the same atoms. They can also study the effect on the physical or biological properties these relationships give molecules.

Why is it called stereochemistry?

The term “stereochemistry” is derived from the Greek “stereos” meaning solid—it refers to chemistry in three dimensions. Since nearly all organic molecules are three dimensional (with the exception of some olefins and aromatics to be discussed later), stereochemistry cannot be considered a branch of chemistry.

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