Question

Find the pH during the titration of 20.00 mL of 0.1000 M triethylamine, (CH₃CH₂)₃N (Kb = 5.2X10⁻⁴), with 0.1000 M HCl solution after the following additions of titrant:(d) 19.00 mL

Answer 1

Ph range is 10.45.

Explanantion:

Initial moles of (CH₃CH₂)₃N = (0.1000 mol/L) × (20.00/1000 L) = 0.002 mol

Moles of HCl added = (0.1000 mol/L) × (13.00/1000 L) = 0.0013 mol

Addition of 1 mole of HCl reacts with 1 mole of (CH₃CH₂)₃N to 1 mole of (CH₃CH₂)₃NH⁺.

After addition of 13.00 mL of HCl:

Moles of (CH₃CH₂)₃N left unreacted = (0.002 - 0.0013) mol = 0.0007 mol

Moles of (CH₃CH₂)₃NH⁺ produced = 0.0013 mol

Hence, [(CH₃CH₂)₃NH⁺]/[(CH₃CH₂)₃N] = 0.0013/0.0007 = 13/7

Consider the dissociation of (CH₃CH₂)₃N:

(CH₃CH₂)₃N(aq) + H₂O(l) ⇌ (CH₃CH₂)₃NH⁺(aq) + OH⁻(aq) …… Kb = 5.2 × 10⁻⁴

Henderson-Hasselbalch equation:

pOH = pKb + log([(CH₃CH₂)₃NH⁺]/[(CH₃CH₂)₃N])

pOH = -log(5.2 × 10⁻⁴) + log(13/7) = 3.55

pH = pKw - pOH = 14.00 - 3.55 = 10.45

What is PH?

PH is a proportion of hydrogen particle focus, a proportion of the causticity or alkalinity of an answer. The pH scale for the most part goes from 0 to 14. Fluid arrangements at 25°C with a pH under 7 are acidic, while those with a pH more prominent than 7 are essential or basic.

The pH is a logarithmic scale, that is to say, when an answer becomes multiple times more acidic, its pH diminishes by one. In the event that an answer becomes multiple times more acidic, its pH will diminish by two. The pH scale is recognizable to a bunch of standard arrangements whose pH is laid out by peaceful accord. Essential pH standard qualities are resolved utilizing a fixation cell with transaction, by estimating the possible distinction between a hydrogen terminal and a standard cathode like the silver chloride anode.

Learn more about PH:

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