Answer:
According to Avogadro's law, the volume of one mole of any gas at Standard Temperature and Pressure (STP = 273 K and 1 atm) is 22.4 L. Two important Gas Laws are required in order to convert the experimentally determined volume of hydrogen gas to that at STP. 1.
Explanation:
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Answer:
ΔS = -661.0J/mol is the entropy change for the system
ΔS = -842J/mol.K is the entropy change for the surroundings
Explanation:
From the relationship between ΔG, T, ΔH and ΔS,
Mathematically, ΔG = ΔH - TΔS
TΔS = ΔH - ΔS
ΔS = ΔH - ΔS / T
but ΔG = -54 kJ/mol, ΔH = -251 kJ/mol and T = 25 °C (298 K)
plugging into the equation,
ΔS = -251 kJ/mol - ( -54 kJ/mol) / 298
ΔS = -0.6610KJ/mol or in J.mol
ΔS = -661.0J/mol is the entropy change for the system
- For entropy change for the surroundings = ΔS = ΔH/T
- ΔS = -0.84KJ/mol.K or -842J/mol.K is the entropy change for the surroundings
Quantity of K2S m = 0.105 m
Number of ions i = 2(K) + 1(S) = 3
Freezing point depression constant of water Kf = 1.86
delta T = i x m x Kf = 3 x 0.105 x 1.86 = 0.586
Freezing point = 0 - 0.586 = 0.586 C
Boiling point constant of water Kb = 0.512
delta T = i x m x Kb = 3 x 0.105 x 0.512 = 0.161
Boiling point = 100 + 0.161 = 100.161 C
Answer:
Reaction A and B are unfavorable.
Explanation:
Gibbs free energy is an energy which that can be use to convert into useful work.
ΔG°=ΔH°-TΔS°
ΔG°= Gibbs free energy
ΔH° = enthalpy of reaction
T = temperature of eh reaction
ΔS° = Entropy change
- If the Gibbs free energy of the reaction is positive than the reaction will be non spontaneous and the chemical reaction will be not feasible.
- If the Gibbs free energy of the reaction is negative than the reaction will be spontaneous and the chemical reaction will be feasible .
According to given information in the question:
Reaction A and B are non spontaneous as their Gibbs free energy value is positive.hence both are unfavorable.