Answer:
1. The pH of 1.0 M trimethyl ammonium (pH = 1.01) is lower than the pH of 0.1 M phenol (5.00).
2. The difference in pH values is 4.95.
Explanation:
1. The pH of a compound can be found using the following equation:
![pH = -log([H_{3}O^{+}])](https://tex.z-dn.net/?f=%20pH%20%3D%20-log%28%5BH_%7B3%7DO%5E%7B%2B%7D%5D%29%20)
First, we need to find [H₃O⁺] for trimethyl ammonium and for phenol.
<u>Trimethyl ammonium</u>:
We can calculate [H₃O⁺] using the Ka as follows:
(CH₃)₃NH⁺ + H₂O → (CH₃)₃N + H₃O⁺
1.0 - x x x
![Ka = \frac{[(CH_{3})_{3}N][H_{3}O^{+}]}{[(CH_{3})_{3}NH^{+}]}](https://tex.z-dn.net/?f=Ka%20%3D%20%5Cfrac%7B%5B%28CH_%7B3%7D%29_%7B3%7DN%5D%5BH_%7B3%7DO%5E%7B%2B%7D%5D%7D%7B%5B%28CH_%7B3%7D%29_%7B3%7DNH%5E%7B%2B%7D%5D%7D)
By solving the above equation for x we have:
x = 0.097 = [H₃O⁺]
![pH = -log([H_{3}O^{+}]) = -log(0.097) = 1.01](https://tex.z-dn.net/?f=%20pH%20%3D%20-log%28%5BH_%7B3%7DO%5E%7B%2B%7D%5D%29%20%3D%20-log%280.097%29%20%3D%201.01%20)
<u>Phenol</u>:
C₆H₅OH + H₂O → C₆H₅O⁻ + H₃O⁺
1.0 - x x x
![Ka = \frac{[C_{6}H_{5}O^{-}][H_{3}O^{+}]}{[C_{6}H_{5}OH]}](https://tex.z-dn.net/?f=Ka%20%3D%20%5Cfrac%7B%5BC_%7B6%7DH_%7B5%7DO%5E%7B-%7D%5D%5BH_%7B3%7DO%5E%7B%2B%7D%5D%7D%7B%5BC_%7B6%7DH_%7B5%7DOH%5D%7D)
Solving the above equation for x we have:
x = 9.96x10⁻⁶ = [H₃O⁺]
![pH = -log([H_{3}O^{+}]) = -log(9.99 \cdot 10^{-6}) = 5.00](https://tex.z-dn.net/?f=%20pH%20%3D%20-log%28%5BH_%7B3%7DO%5E%7B%2B%7D%5D%29%20%3D%20-log%289.99%20%5Ccdot%2010%5E%7B-6%7D%29%20%3D%205.00%20)
Hence, the pH of 1.0 M trimethyl ammonium is lower than the pH of 0.1 M phenol.
2. The difference in pH values for the two acids is:
Therefore, the difference in pH values is 4.95.
I hope it helps you!
The researcher may first weight the beaker with water and then start to heat the water to a constant temperature, for example 30 °C and then start adding salt and stirring. He should add salt slowly until solid salt starts to become visible and the solution starts becoming cloudy. When this happens, he should quickly weigh the beaker. The increase in mass is the mass of salt dissolved at that temperature.
The procedure is then repeated but at an increased temperature until 5-6 temperatures have been tested.
The Octet rule is a general rule of thumb that applies to most atoms. Basically, it states that every atom wants to have eight valence electrons in its outermost electron shell.
Given :
The distance between a point charge and a neutral atom and is multiplied by a factor of 5.
To Find :
By what factor does the force on the neutral atom by the point charge change.
Solution :
We know, electrostatic force between two object is directly proportional to product of charge and inversely proportional to distance between them.
Now, charge in neutral atom is 0 C.
So, the electrostatic force between two of them is also 0 N.
Therefore, by changing distance between the charge the forces did no change ( it remains zero).
Answer:
[Na₂CO₃] = 0.094M
Explanation:
Based on the reaction:
HCO₃⁻(aq) + H₂O(l) ↔ CO₃²⁻(aq) + H₃O⁺(aq)
It is possible to find pH using Henderson-Hasselbalch formula:
pH = pka + log₁₀ [A⁻] / [HA]
Where [A⁻] is concentration of conjugate base, [CO₃²⁻] = [Na₂CO₃] and [HA] is concentration of weak acid, [NaHCO₃] = 0.20M.
pH is desire pH and pKa (<em>10.00</em>) is -log pka = -log 4.7x10⁻¹¹ = <em>10.33</em>
<em />
Replacing these values:
10.00 = 10.33 + log₁₀ [Na₂CO₃] / [0.20]
<em> [Na₂CO₃] = 0.094M</em>
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