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1 year ago

Hello I’m having trouble with this question May you help me? Thank you!

Chemistry

1 answer:

Ostrovityanka [42]1 year ago

4 0

Answer:

Explanation:

Here, we want to state the similarity between the model by Rutherford and the model by Thompson

The similarity in both models can be seen in terms of the affirmation of the presence of positively and neatively charged units in the atom

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CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at 25 ∘C under these conditions: PCO2PCCl4PCOCl2===0.140 atm0.185 atm0.7

padilas [110]

<u>Answer:</u> The $\Delta G$ for the reaction is 54.425 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

$CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)$

We are given:

$\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol$

To calculate $\Delta G^o_{rxn}$ for the reaction, we use the equation:

$\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]$

For the given equation:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]$

Putting values in above equation, we get:

$\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J$

Conversion factor used = 1 kJ = 1000 J

The expression of $K_p$ for the given reaction:

$K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}$

We are given:

$p_{COCl_2}=0.735atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.185atm$

Putting values in above equation, we get:

$K_p=\frac{(0.735)^2}{0.410\times 0.185}\\\\K_p=20.85$

To calculate the gibbs free energy of the reaction, we use the equation:

$\Delta G=\Delta G^o+RT\ln K_p$

where,

$\Delta G$ = Gibbs' free energy of the reaction = ?

$\Delta G^o$ = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = $8.314J/K mol$

T = Temperature = $25^oC=[25+273]K=298K$

$K_p$ = equilibrium constant in terms of partial pressure = 20.85

Putting values in above equation, we get:

$\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(20.85))\\\\\Delta G=54425.26J/mol=54.425kJ/mol$

Hence, the $\Delta G$ for the reaction is 54.425 kJ/mol

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3 years ago

Boiling occurs when molecules being changed from liquid to gas plz tell me the answer true or false

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Answer:

Liquid to Gas

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3 years ago

A zinc block with a mass of 230 g is given 1320 J of energy. What is the change in

Mariana [72]

Answer:

14.7°C

Explanation: